| CAS Number: | 12190-79-3 |
| MDL Number: | MFCD00049786 |
| Molecular Formula: | CoLiO2 |
| Molecular Weight: | 97.87 |
| Chemical Formula: | LiCoO2 |
| Color and Form: | dark gray pwdr. |
| Note: |
| SECTION 1: Product Identification | |
|---|---|
| Chemical Name: | Lithium cobalt (III) oxide, min. 98% |
| Product Number: | 93-0386 |
| CAS Registry Number: | 12190-79-3 |
| Formula: | LiCoO2 |
| EINECS Number: | 235-362-0 |
| Chemical Family: | metal oxide |
| Synonym: | Lithium cobaltite. Lithium oxide, cobalt oxide co-compound |
| SECTION 2: Composition and Information on Ingredients | ||||
|---|---|---|---|---|
| Ingredient | CAS Number | Percent | ACGIH (TWA) | OSHA (PEL) |
| Title Compound | 12190-79-3 | 100 | 0.02mg/m3 (as Co) | no data |
| SECTION 3: Hazards Identification | |
|---|---|
| Emergency Overview: | Lithium is toxic to the central nervous system. Repeated ingestion may damage kidneys and act as a teratogen. May be irritating to skin, eyes and respiratory tract. Limited evidence of a carcinogenic effect. |
| Primary Routes of Exposure: | Ingestion, inhalation, skin and eyes |
| Eye Contact: | May cause severe irritation of the eyes resulting in redness, chemical burns and watering. |
| Skin Contact: | Prolonged contact with moist skin may cause irritation. May cause sensitization by skin contact. |
| Inhalation: | May be irritating to the nose, mucous membranes and respiratory tract. |
| Ingestion: | May be harmful if swallowed. Ingestion of large amounts may cause stomach cramps, vomiting, and ulceration. |
| Acute Health Effects: | May be irritating to skin, eyes and respiratory tract. |
| Chronic Health Effects: | Lithium may cause kidney damage and may be a teratogen. Limited evidence of a carcinogenic effect. |
| NTP: | No |
| IARC: | Yes |
| OSHA: | No |
| SECTION 4: First Aid Measures | |
|---|---|
| Eye Exposure: | Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention. |
| Skin Exposure: | Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists. |
| Inhalation: | Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. |
| Ingestion: | Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel. |
| SECTION 5: Fire Fighting Measures | |
|---|---|
| Flash Point: | not applicable |
| Autoignition Temperature: | none |
| Explosion Limits: | none |
| Extinguishing Medium: | None. Material is non-flammable. |
| Special Fire Fighting Procedures: | No special fire-fighting procedures. The material is non-flammable. |
| Hazardous Combustion and Decomposion Products: | No hazardous combustion or decomposition products. |
| Unusual Fire or Explosion Hazards: | No unusual fire or explosion hazards. |
| SECTION 6: Accidental Release Measures | |
|---|---|
| Spill and Leak Procedures: | Small spills can be mixed with vermiculite or sodium carbonate and swept up. |
| SECTION 7: Handling and Storage | |
|---|---|
| Handling and Storage: | No special storage conditions. |
| SECTION 8: Exposure Controls and Personal Protection | |
|---|---|
| Eye Protection: | Always wear approved safety glasses when handling a chemical substance in the laboratory. |
| Skin Protection: | Wear appropriate chemical resistant gloves and protective clothing. |
| Ventilation: | Material may form a fine dust. If possible, handle the material in an efficient fume hood. |
| Respirator: | If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134. |
| Additional Protection: | No additional protection required. |
| SECTION 9: Physical and Chemical Properties | |
|---|---|
| Color and Form: | dark gray pwdr. |
| Molecular Weight: | 97.87 |
| Melting Point: | no data |
| Boiling Point: | no data |
| Vapor Pressure: | not applicable |
| Specific Gravity: | no data |
| Odor: | none |
| Solubility in Water: | insoluble |
| SECTION 10: Stability and Reactivity | |
|---|---|
| Stability: | air and moisture stable |
| Hazardous Polymerization: | no hazardous polymerization |
| Conditions to Avoid: | none |
| Incompatibility: | mineral acids |
| Decomposition Products: | none |
| SECTION 11: Toxicological Information | |
|---|---|
| RTECS Data: | No information available in the RTECS files. |
| Carcinogenic Effects: | Possible carcinogen (as Co) |
| Mutagenic Effects: | No data available |
| Tetratogenic Effects: | No data available |
| SECTION 12: Ecological Information | |
|---|---|
| Ecological Information: | Avoid release to the environment. Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. |
| SECTION 13: Disposal Considerations | |
|---|---|
| Disposal: | This material and its container must be disposed of as hazardous waste according to local, state and federal regulations. |
| SECTION 14: Transportation | |
|---|---|
| Shipping Name (CFR): | Non-hazardous |
| Hazard Class (CFR): | NA |
| Additional Hazard Class (CFR): | NA |
| Packaging Group (CFR): | NA |
| UN ID Number (CFR): | NA |
| Shipping Name (IATA): | Non-hazardous |
| Hazard Class (IATA): | NA |
| Additional Hazard Class (IATA): | NA |
| Packaging Group (IATA): | NA |
| UN ID Number (IATA): | NA |
| SECTION 15: Regulatory Information | |
|---|---|
| TSCA: | Listed in the TSCA inventory. |
| SARA (Title 313): | Title compound: See Category Code N096 for reporting. |
| Second Ingredient: | none |
| Third Ingredient: | none |
| SECTION 16: Other Information | |
|---|---|
| Disclaimer: | The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information. |
| Preparation Date: | 3/20/2001 |
| Revision Date: | 8/22/2011 |