CAS Number: 7439-93-2
Product Catalog

93-0369

Lithium › Lithium ribbon (99.8%)

Stability: air sensitive, moisture sensitive

Safety: Hazardous

Physical Characteristics: melting point 179°C, boiling point 1317°C, density 0.534

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SECTION 1: Product Identification
Chemical Name:	Lithium ribbon (99.8%)
Product Number:	93-0369
CAS Registry Number:	7439-93-2
Formula:	Li
EINECS Number:	231-102-5
Chemical Family:	metal or element
Synonym:	Alkali metal

SECTION 2: Composition and Information on Ingredients
Ingredient	CAS Number	Percent	ACGIH (TWA)	OSHA (PEL)
Title Compound	7439-93-2	100	no data	no data
mineral oil	8042-47-5		no data	no data

SECTION 3: Hazards Identification
Emergency Overview:	Causes burns to eyes, skin and respiratory tract. Mineral oil may be harmful if swallowed, an irritant, and possible tumorigen.
Primary Routes of Exposure:	Ingestion, inhalation of any dust.
Eye Contact:	Oil, and dust, if present, causes burns to the eyes.
Skin Contact:	Dust, if present, causes burns to the skin.
Inhalation:	Inhalation of any oil free fine dust is corrosive to the nasal cavity, mucous membranes and respiratory tract.
Ingestion:	No specific information is available on the physiological effects of ingestion. Mineral oil may be harmful.
Acute Health Effects:	Oil free dust, if present, is corrosive to skin, eyes and respiratory tract. Moderately caustic alkaline surface oxides may irritate the skin.
Chronic Health Effects:	No information available on long-term chronic effects. Impurities in some mineral oils may be tumorigens.
NTP:	No
IARC:	No
OSHA:	No

SECTION 4: First Aid Measures
Eye Exposure:	Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention.
Skin Exposure:	Wash the affected area with water for at least 15 minutes. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists.
Inhalation:	(For dust or fume) Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing or coughing. In such cases seek immediate medical assistance.
Ingestion:	Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:	not applicable
Autoignition Temperature:	no data
Explosion Limits:	no data
Extinguishing Medium:	Class D metal fire agent, dry salt or sand.
Special Fire Fighting Procedures:	If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus.
Hazardous Combustion and Decomposion Products:	If involved in a fire, burning metal may produce moderately corrosive fumes of lithium oxide and hydroxide.
Unusual Fire or Explosion Hazards:	Flammable solid. Burns with intense heat. Dust may form explosive mixtures with air. Evolves flammable hydrogen with water.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:	Not applicable; material is metal ribbon. Mineral oil is a slipping hazard.

SECTION 7: Handling and Storage
Handling and Storage:	Store in a tightly sealed container in argon under mineral oil, in a cool dry place. Handle in Argon.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:	Always wear approved chemical splash proof goggles.
Skin Protection:	Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.
Ventilation:	If converted to a fine oil free dust, handle the material in an efficient fume hood.
Respirator:	If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Additional Protection:	Prepare for the possibility of fire.

SECTION 9: Physical and Chemical Properties
Color and Form:	100 mm wide x 1.5 mm thick
Molecular Weight:	6.94
Melting Point:	179°C
Boiling Point:	1317°C
Vapor Pressure:	1mm (723 °C)
Specific Gravity:	0.534
Odor:	none
Solubility in Water:	Reacts violently with water

SECTION 10: Stability and Reactivity
Stability:	air sensitive, moisture sensitive
Hazardous Polymerization:	no hazardous polymerization
Conditions to Avoid:	Contact with water or of any oil free fine dust with air.
Incompatibility:	Water, alcohols, oxidizers, oxygen, carbon dioxide, halogens, halocarbons, acids.
Decomposition Products:	Carbon dioxide, carbon monoxide, organic fumes.

SECTION 11: Toxicological Information
RTECS Data:	Intraperitoneal (mouse); LD50: 1 gm/kg. Unreported (human); Cytogenetic analysis: 714 mg/kg/8W (intermittent).
Carcinogenic Effects:	Mineral oil : Possible Tumorigen
Mutagenic Effects:	No data available
Tetratogenic Effects:	No data available

SECTION 12: Ecological Information
Ecological Information:	No information available

SECTION 13: Disposal Considerations
Disposal:	Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):	Lithium
Hazard Class (CFR):	4.3
Additional Hazard Class (CFR):	NA
Packaging Group (CFR):	I
UN ID Number (CFR):	UN# 1415
Shipping Name (IATA):	Lithium
Hazard Class (IATA):	4.3
Additional Hazard Class (IATA):	NA
Packaging Group (IATA):	I
UN ID Number (IATA):	UN# 1415

SECTION 15: Regulatory Information
TSCA:	Listed in the TSCA inventory
SARA (Title 313):	Title compound not listed
Second Ingredient:	mineral oil listed in TSCA
Third Ingredient:	none

SECTION 16: Other Information
Disclaimer:	The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information.
Preparation Date:	11/27/2000
Revision Date:	8/01/2011