| CAS Number: | 7782-89-0 |
| MDL Number: | MFCD00011093 |
| Molecular Formula: | H2LiN |
| Molecular Weight: | 22.96 |
| Chemical Formula: | LiNH2 |
| Color and Form: | off-white pwdr. |
| Note: |
Stability: air sensitive, moisture sensitive
Safety: Hazardous
Physical Characteristics: melting point 373-375°C, density 1.178
| SECTION 1: Product Identification | |
|---|---|
| Chemical Name: | Lithium amide, 95% |
| Product Number: | 93-0306 |
| CAS Registry Number: | 7782-89-0 |
| Formula: | LiNH2 |
| EINECS Number: | 231-968-4 |
| Chemical Family: | metal amide |
| Synonym: | none |
| SECTION 2: Composition and Information on Ingredients | ||||
|---|---|---|---|---|
| Ingredient | CAS Number | Percent | ACGIH (TWA) | OSHA (PEL) |
| Title Compound | 7782-89-0 | 100 | no data | no data |
| SECTION 3: Hazards Identification | |
|---|---|
| Emergency Overview: | Material is corrosive to skin, eyes, and mucous membranes. |
| Primary Routes of Exposure: | Ingestion, inhalation |
| Eye Contact: | Causes burns to the eyes |
| Skin Contact: | Causes burns to the skin. |
| Inhalation: | Corrosive to the nose, mucous membranes and respiratory tract. |
| Ingestion: | No information on the physiological effects of ingestion. |
| Acute Health Effects: | Corrosive to skin, eyes and respiratory tract. |
| Chronic Health Effects: | No information available on long-term chronic effects. |
| NTP: | No |
| IARC: | No |
| OSHA: | No |
| SECTION 4: First Aid Measures | |
|---|---|
| Eye Exposure: | Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention. |
| Skin Exposure: | Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists. |
| Inhalation: | Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. |
| Ingestion: | Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel. |
| SECTION 5: Fire Fighting Measures | |
|---|---|
| Flash Point: | not applicable |
| Autoignition Temperature: | none |
| Explosion Limits: | none |
| Extinguishing Medium: | carbon dioxide, foam or dry powder |
| Special Fire Fighting Procedures: | If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus and full protective clothing. |
| Hazardous Combustion and Decomposion Products: | If involved in a fire this material may emit irritating fumes. |
| Unusual Fire or Explosion Hazards: | Product is a flammable solid. No unusual explosion hazards. |
| SECTION 6: Accidental Release Measures | |
|---|---|
| Spill and Leak Procedures: | Small spills can be mixed with vermiculite or sodium carbonate and swept up. |
| SECTION 7: Handling and Storage | |
|---|---|
| Handling and Storage: | Store in a tightly sealed container. Keep away from heat and direct sunlight. Material may react with atmospheric moisture and lead to degradation of the product. |
| SECTION 8: Exposure Controls and Personal Protection | |
|---|---|
| Eye Protection: | Always wear approved safety glasses when handling a chemical substance in the laboratory. |
| Skin Protection: | Wear protective clothes and gloves. |
| Ventilation: | If possible, handle the material in an efficient fume hood. |
| Respirator: | In the absence of adequate ventilation a respirator should be worn. The use of a respirator requires a Respiratory Protection Program to be in compliance with 29 CFR 1910.134. |
| Additional Protection: | No additional protection required. |
| SECTION 9: Physical and Chemical Properties | |
|---|---|
| Color and Form: | off-white pwdr. |
| Molecular Weight: | 22.96 |
| Melting Point: | 373-375°C |
| Boiling Point: | no data |
| Vapor Pressure: | no data |
| Specific Gravity: | 1.178 |
| Odor: | none |
| Solubility in Water: | reacts violently with water |
| SECTION 10: Stability and Reactivity | |
|---|---|
| Stability: | air sensitive, moisture sensitive |
| Hazardous Polymerization: | no hazardous polymerization |
| Conditions to Avoid: | prolonged contact with air and moisture. |
| Incompatibility: | Water, air, alcohols, active metals, oxidizing agents and halogens |
| Decomposition Products: | nitrogen oxides and lithium salts. |
| SECTION 11: Toxicological Information | |
|---|---|
| RTECS Data: | No information available in the RTECS files. |
| Carcinogenic Effects: | No data available |
| Mutagenic Effects: | No data available |
| Tetratogenic Effects: | No data available |
| SECTION 12: Ecological Information | |
|---|---|
| Ecological Information: | No information available |
| SECTION 13: Disposal Considerations | |
|---|---|
| Disposal: | Dispose of in accordance with local, state, and federal regulations. |
| SECTION 14: Transportation | |
|---|---|
| Shipping Name (CFR): | Alkali metal amides |
| Hazard Class (CFR): | 4.3 |
| Additional Hazard Class (CFR): | NA |
| Packaging Group (CFR): | II |
| UN ID Number (CFR): | UN# 1390 |
| Shipping Name (IATA): | Alkali metal amides |
| Hazard Class (IATA): | 4.3 |
| Additional Hazard Class (IATA): | NA |
| Packaging Group (IATA): | II |
| UN ID Number (IATA): | UN# 1390 |
| SECTION 15: Regulatory Information | |
|---|---|
| TSCA: | Listed in the TSCA inventory. |
| SARA (Title 313): | Title compound not listed. |
| Second Ingredient: | none |
| Third Ingredient: | none |
| SECTION 16: Other Information | |
|---|---|
| Disclaimer: | The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information. |
| Preparation Date: | 6/05/2000 |
| Revision Date: | 8/01/2011 |