| CAS Number: | 7446-18-6 |
| MDL Number: | MFCD00011278 |
| Molecular Formula: | O4STl2 |
| Molecular Weight: | 504.80 |
| Chemical Formula: | Tl2SO4 |
| Color and Form: | white xtl. |
| Note: |
Safety: Hazardous
Physical Characteristics: melting point 632°C, boiling point dec., density 6.77
| SECTION 1: Product Identification | |
|---|---|
| Chemical Name: | Thallium (I) sulfate (99.999%-Tl) PURATREM |
| Product Number: | 81-8200 |
| CAS Registry Number: | 7446-18-6 |
| Formula: | Tl2SO4 |
| EINECS Number: | 231-201-3 |
| Chemical Family: | metal sulfate |
| Synonym: | Dithallium sulfate |
| SECTION 2: Composition and Information on Ingredients | ||||
|---|---|---|---|---|
| Ingredient | CAS Number | Percent | ACGIH (TWA) | OSHA (PEL) |
| Title Compound | 7446-18-6 | 100 | 0.1mg/m3 | 0.1mg/m3 |
| SECTION 3: Hazards Identification | |
|---|---|
| Emergency Overview: | Thallium compounds, especially if water soluble, are highly poisonous by ingestion. Thallium compounds have been used as a rat poison. |
| Primary Routes of Exposure: | Ingestion |
| Eye Contact: | May cause slight to mild irritation of the eyes. |
| Skin Contact: | May cause slight to mild irritation of the skin. Harmful in contact with skin. |
| Inhalation: | May be irritating to the nose, mucous membranes and respiratory tract. Thallium poisoning may occur. |
| Ingestion: | Ingestion may result in swelling of the feet and legs, mental confusion, paralysis and angina-like pains. Very toxic if swallowed. |
| Acute Health Effects: | Acute poisoning, after 1-10 days, results in pain of the extremities, fever, difficulty in moving, vomiting, followed by jumbled speech, tremors, convulsions, kidney failure, and pulmonary edema. |
| Chronic Health Effects: | Prolonged exposure to thallium compounds has been reported to lead to discoloration of the hair, which later falls out, joint pain, loss of appetite, fatigue, severe pain in the legs, albuminuria, and optic neuritis. Possible mutagen. |
| NTP: | No |
| IARC: | No |
| OSHA: | No |
| SECTION 4: First Aid Measures | |
|---|---|
| Eye Exposure: | Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention. |
| Skin Exposure: | Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists. |
| Inhalation: | Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. |
| Ingestion: | Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel. |
| SECTION 5: Fire Fighting Measures | |
|---|---|
| Flash Point: | not applicable |
| Autoignition Temperature: | none |
| Explosion Limits: | none |
| Extinguishing Medium: | none required |
| Special Fire Fighting Procedures: | If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus and full protective clothing. |
| Hazardous Combustion and Decomposion Products: | If involved in a fire this material may emit toxic fumes of sulfur oxides. |
| Unusual Fire or Explosion Hazards: | No unusual fire or explosion hazards. |
| SECTION 6: Accidental Release Measures | |
|---|---|
| Spill and Leak Procedures: | Small spills can be mixed with powdered sodium carbonate or ground limestone and swept up. |
| SECTION 7: Handling and Storage | |
|---|---|
| Handling and Storage: | Store material in a tightly sealed bottle away from moisture. |
| SECTION 8: Exposure Controls and Personal Protection | |
|---|---|
| Eye Protection: | Always wear approved safety glasses when handling a chemical substance in the laboratory. |
| Skin Protection: | Wear appropriate chemical resistant gloves and protective clothing. |
| Ventilation: | If possible, handle the material in an efficient fume hood. |
| Respirator: | In the absence of adequate ventilation a respirator should be worn. The use of a respiratory requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134. |
| Additional Protection: | No additional protection required. |
| SECTION 9: Physical and Chemical Properties | |
|---|---|
| Color and Form: | white xtl. |
| Molecular Weight: | 504.8 |
| Melting Point: | 632°C |
| Boiling Point: | dec. |
| Vapor Pressure: | not applicable |
| Specific Gravity: | 6.77 |
| Odor: | none |
| Solubility in Water: | 4.87g/100cc (20°C) |
| SECTION 10: Stability and Reactivity | |
|---|---|
| Stability: | air and moisture stable |
| Hazardous Polymerization: | no hazardous polymerization |
| Conditions to Avoid: | none |
| Incompatibility: | none |
| Decomposition Products: | none |
| SECTION 11: Toxicological Information | |
|---|---|
| RTECS Data: | Oral (human-man); LDLo: 3 mg/kg. Oral (human-man); TDLo: 7 ug/kg. Oral (human-man); LDLo: 14 mg/kg. Oral (human); LDLo: 2166 ug/kg. Oral (rat); LD50: 16 mg/kg. Administration onto the skin (rat); LD50: 550 mg/kg. Subcutaneous (rat); LDLo: 13 mg/kg. Oral (dog); LDLo; 16 mg/kg. Oral (rat); TDLo: 9 mg/kg/15D-I. Oral (rat); TDLo: 57 mg/kg. |
| Carcinogenic Effects: | no data |
| Mutagenic Effects: | no data |
| Tetratogenic Effects: | reproductive effector |
| SECTION 12: Ecological Information | |
|---|---|
| Ecological Information: | Avoid release to the environment. very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. |
| SECTION 13: Disposal Considerations | |
|---|---|
| Disposal: | Dispose of according to local, state and federal regulations. |
| SECTION 14: Transportation | |
|---|---|
| Shipping Name (CFR): | Thallium Compounds, N.O.S. |
| Hazard Class (CFR): | 6.1 |
| Additional Hazard Class (CFR): | NA |
| Packaging Group (CFR): | II |
| UN ID Number (CFR): | UN# 1707 |
| Shipping Name (IATA): | Thallium Compound, N.O.S. |
| Hazard Class (IATA): | 6.1 |
| Additional Hazard Class (IATA): | NA |
| Packaging Group (IATA): | II |
| UN ID Number (IATA): | UN# 1707 |
| SECTION 15: Regulatory Information | |
|---|---|
| TSCA: | Listed in the TSCA inventory |
| SARA (Title 313): | Title compound: See category code N760 for reporting. |
| Second Ingredient: | none |
| Third Ingredient: | none |
| SECTION 16: Other Information | |
|---|---|
| Disclaimer: | The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information. |
| Preparation Date: | 10/08/2001 |
| Revision Date: | 8/02/2011 |