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CAS Number: 13454-96-1
Product Catalog

78-1490
Platinum Platinum(IV) chloride (99.9%-Pt)
CAS Number: 13454-96-1
MDL Number: MFCD00011182
Molecular Formula: Cl4Pt
Molecular Weight: 336.90
Chemical Formula: PtCl4
Color and Form: reddish-brown xtl.
Note:  

Stability: moisture sensitive

Safety: Hazardous

Physical Characteristics: melting point 370°C dec., density 4.303

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SECTION 1: Product Identification
Chemical Name: Platinum (IV) chloride (99.9%-Pt)
Product Number: 78-1490
CAS Registry Number: 13454-96-1
Formula: PtCl4
EINECS Number: 236-645-1
Chemical Family: metal halide
Synonym: Platinum tetrachloride, tetrachloroplatinum, platinic chloride
SECTION 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title Compound 13454-96-1 100 0.002mg/m3 0.002mg/m3
SECTION 3: Hazards Identification
Emergency Overview: Exposure to platinum salts has been shown to cause wheezing, coughing, shortness of breath and running of the nose. Harmful if swallowed. Causes burns. Skin contact can lead to dermatitis.
Primary Routes of Exposure: Ingestion, skin, inhalation of dust
Eye Contact: Causes burns to the eyes.
Skin Contact: Causes slight burns to the skin. May cause dermatitis. Can induce an allergic reaction.
Inhalation: Inhalation of dust may cause wheezing, coughing, shortness of breath and asthma like symptoms. Caues burns to the respiratory tract.
Ingestion: Ingestion may lead to dizziness, abdominal cramps, and vomiting. Harmful if swallowed.
Acute Health Effects: Upon repeated exposure certain persons may develop an allergic reaction to chloroplatinates, causing wheezing, coughing, shortness of breath and runny nose. Causes burns. Harmful if swallowed.
Chronic Health Effects: The chloroplatinate allergic reaction known as platinosis ceases when exposure is terminated. No permanent long term effects are reported. May cause heritable genetic damage.
NTP: No
IARC: No
OSHA: No
SECTION 4: First Aid Measures
Eye Exposure: Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention.
Skin Exposure: Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists.
Inhalation: Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Ingestion: Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel.
SECTION 5: Fire Fighting Measures
Flash Point: not applicable
Autoignition Temperature: none
Explosion Limits: none
Extinguishing Medium: None. Material is non-flammable.
Special Fire Fighting Procedures: No special fire fighting procedures required.
Hazardous Combustion and Decomposion Products: If involved in a fire this material may emit toxic fumes of chlorine gas and hydrogen chloride.
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.
SECTION 6: Accidental Release Measures
Spill and Leak Procedures: To avoid raising dust, small spills may be mixed with diatomaceous earth, sand, vermiculite or other suitable inert material and swept up.
SECTION 7: Handling and Storage
Handling and Storage: Store solid in a tightly sealed container away from moisture. Handle under a dry atmosphere of air or nitrogen. Prolonged exposure to the atmosphere may degrade the product.
SECTION 8: Exposure Controls and Personal Protection
Eye Protection: Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection: Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.
Ventilation: Material may form a fine dust. If possible, handle the material in an efficient fume hood.
Respirator: If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Additional Protection: No additional protection required.
SECTION 9: Physical and Chemical Properties
Color and Form: reddish-brown xtl.
Molecular Weight: 336.9
Melting Point: 370°C dec.
Boiling Point: no data
Vapor Pressure: not applicable
Specific Gravity: 4.303
Odor: none
Solubility in Water: insoluble
SECTION 10: Stability and Reactivity
Stability: moisture sensitive
Hazardous Polymerization: no hazardous polymerization
Conditions to Avoid: contact with moisture
Incompatibility: oxidizing agents and active metals
Decomposition Products: Chloroplatinic acid, platinum dichloride, hydrogen chloride, chlorine
SECTION 11: Toxicological Information
RTECS Data: Administration onto the skin (rabbit); Standard Draize test: 100 mg/24H. Oral (rat); LD50: 276 mg/kg. Intratesticular (rat); TDLo: 26951 ug/kg. Subcutaneous (mouse); TDLo: 26951 ug/kg. Bacteria-Salmonella typhimurim; Mutation in microorganisms: 100 ng/disc. Bacteria-Escherichia coli; Mutation test systems-not otherwise specified: 100 umol/L. Bacteria-Bacillus subtilis; DNA repair: 1 mmol/L. Oral (insect-Drosophila melanogaster); Sex chromosome loss and nondisjunction: 300 umol/L/72H. Human Lymphocyte; Micronucleus test: 20 umol/L. Human Lung; DNA inhibition: 2300 ug/L. Intraperitoneal (rat); DNA inhibition:28 umol/kg.
Carcinogenic Effects: no data
Mutagenic Effects: Mutagen
Tetratogenic Effects: Insufficient data
SECTION 12: Ecological Information
Ecological Information: No information available
SECTION 13: Disposal Considerations
Disposal: Dispose of according to local, state and federal regulations.
SECTION 14: Transportation
Shipping Name (CFR): Corrosive solid, Acidic, Inorganic, N.O.S.
Hazard Class (CFR): 8
Additional Hazard Class (CFR): NA
Packaging Group (CFR): III
UN ID Number (CFR): UN# 3260
Shipping Name (IATA): Corrosive solid, Acidic, Inorganic, N.O.S.
Hazard Class (IATA): 8
Additional Hazard Class (IATA): NA
Packaging Group (IATA): III
UN ID Number (IATA): UN# 3260
SECTION 15: Regulatory Information
TSCA: Listed in the TSCA inventory.
SARA (Title 313): Title compound not listed.
Second Ingredient: none
Third Ingredient: none
SECTION 16: Other Information
Disclaimer: The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information.
Preparation Date: 6/07/2001
Revision Date: 3/07/2011

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