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CAS Number: 261948-85-0

44-0153
Ruthenium › Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(S)-binap]
CAS Number: 261948-85-0
MDL Number: MFCD09753020
Molecular Formula: C48H38O4P2Ru
Molecular Weight: 841.83
Chemical Formula: C48H38O4P2Ru
Color and Form: pale yellow pwdr.
Note: Manufactured under license of Takasago patent. Takasago BINAP Ru Acetate Catalyst Kit component

Stability: air sensitive

44-0153

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Download This MSDS
SECTION 1: Product Identification
Chemical Name: Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(S)-binap]
Product Number: 44-0153
CAS Registry Number: 261948-85-0
Formula: C48H38O4P2Ru
EINECS Number: none
Chemical Family: metal phosphine complex
Synonym: {Ru(OAc)2{(S)-binap}]
SECTION 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title compound 261948-85-0 100 no data no data
SECTION 3: Hazards Identification
Emergency Overview: Irritating to skin, eyes and respiratory tract.
Primary Routes of Exposure: Inhalation, skin, eyes
Eye Contact: Causes slight to mild irritation of the eyes.
Skin Contact: Causes irritation to the skin
Inhalation: Causes irritation to the nose, mucous membranes and respiratory tract
Ingestion: No information on the physiological effects of ingestion. May be harmful if swallowed.
Acute Health Effects: Irritating to skin, eyes and respiratory tract.
Chronic Health Effects: No information available on long-term chronic effects
NTP: No
IARC: No
OSHA: No
SECTION 4: First Aid Measures
Eye Exposure: Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention.
Skin Exposure: Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists.
Inhalation: Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Ingestion: Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel.
SECTION 5: Fire Fighting Measures
Flash Point: no data
Autoignition Temperature: no data
Explosion Limits: no data
Extinguishing Medium: carbon dioxide, dry chemical or foam
Special Fire Fighting Procedures: If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus and full protective clothing.
Hazardous Combustion and Decomposion Products: If involved in a fire, this material may emit toxic organic fumes
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards
SECTION 6: Accidental Release Measures
Spill and Leak Procedures: Small spills can be mixed with vermiculite, sodium carbonate or other suitable non-combustible adsorbent and swept up.
SECTION 7: Handling and Storage
Handling and Storage: Keep material in a tightly sealed container. Prolonged exposure to the air may result in degradation of the product. Handle and store material under an inert atmosphere of nitrogen or argon.
SECTION 8: Exposure Controls and Personal Protection
Eye Protection: Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection: Wear protective clothing and gloves.
Ventilation: Handle the material in an efficient fume hood.
Respirator: If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Additional Protection: No additional protection required.
SECTION 9: Physical and Chemical Properties
Color and Form: pale yellow powder
Molecular Weight: 841.83
Melting Point: >100? (decomp)
Boiling Point: no data
Vapor Pressure: no data
Specific Gravity: no data
Odor: not determined
Solubility in Water: insoluble
SECTION 10: Stability and Reactivity
Stability: air sensitive
Hazardous Polymerization: no hazardous polymerization
Conditions to Avoid: contact with air
Incompatibility: strong oxidizing agents
Decomposition Products: carbon monoxide, carbon dioxide, phosphorous pentoxide, organic fumes and ruthenium salts.
SECTION 11: Toxicological Information
RTECS Data: No information available in the RTECS files
Carcinogenic Effects: no data
Mutagenic Effects: no data
Tetratogenic Effects: no data
SECTION 12: Ecological Information
Ecological Information: No information available
SECTION 13: Disposal Considerations
Disposal: Dispose of according to local, state and federal regulations
SECTION 14: Transportation
Shipping Name (CFR): Non-hazardous
Hazard Class (CFR): NA
Additional Hazard Class (CFR): NA
Packaging Group (CFR): NA
UN ID Number (CFR): NA
Shipping Name (IATA): Non-hazardous
Hazard Class (IATA): NA
Additional Hazard Class (IATA): NA
Packaging Group (IATA): NA
UN ID Number (IATA): NA
SECTION 15: Regulatory Information
TSCA: Not listed in the TSCA inventory
SARA (Title 313): Title compound not listed
Second Ingredient: none
Third Ingredient: none
SECTION 16: Other Information
Disclaimer: The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information.
Preparation Date: 5/24/2007
Revision Date: 3/02/2010

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