| CAS Number: | 557-20-0 |
| MDL Number: | MFCD00009021 |
| Molecular Formula: | C4H10Zn |
| Molecular Weight: | 123.49 |
| Chemical Formula: | Zn(C2H5)2 |
| Color and Form: | colorless liq. |
| Note: |
Stability: air sensitive, moisture sensitive
Safety: Hazardous
| SECTION 1: Product Identification | |
|---|---|
| Chemical Name: | Diethylzinc, min. 95% (10 wt% in hexane) (Sure/Seal TM Bottle) |
| Product Number: | 30-3029 |
| CAS Registry Number: | 557-20-0 |
| Formula: | Zn(C2H5)2 |
| EINECS Number: | 209-161-3 |
| Chemical Family: | metal alkyl |
| Synonym: | None |
| SECTION 2: Composition and Information on Ingredients | ||||
|---|---|---|---|---|
| Ingredient | CAS Number | Percent | ACGIH (TWA) | OSHA (PEL) |
| Title Compound | 557-20-0 | 10 | 5 mg/m3 (fume) | 5 mg/m3 (fume) |
| hexane | 110-54-3 | 90 | 50ppm | 1800mg/m3 |
| SECTION 3: Hazards Identification | |
|---|---|
| Emergency Overview: | Extremely flammable liquid. Vapors irritating to eyes and respiratory tract and may depress central nervous system causing dizziness, headache and nausea. Liquid may cause thermal burns to skin and eyes. |
| Primary Routes of Exposure: | Eyes, skin, and inhalation of combustion products. |
| Eye Contact: | Direct contact of liquid with the eyes will cause irritation. May cause thermal burns and possible blindness. |
| Skin Contact: | Irritating to skin. Residue upon evaporation of hexane may burst into flame causing thermal burns. |
| Inhalation: | Inhalation of vapors may depress the central nervous system causing dizziness, difficulty in walking, and irritation to the lungs. |
| Ingestion: | Ingestion may cause gastrointestinal irritation, nausea, vomiting and headache. |
| Acute Health Effects: | Irritation to skin, eyes and respiratory tract. Ingestion may cause gastrointestinal irritation, nausea, vomiting and headache. Possible risk of harm to the unborn child. |
| Chronic Health Effects: | Possible risk of impaired fertility. Prolonged inhalation may cause laryngitis. Prolonged ingestion may cause constipation. |
| NTP: | No |
| IARC: | No |
| OSHA: | No |
| SECTION 4: First Aid Measures | |
|---|---|
| Eye Exposure: | Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention. |
| Skin Exposure: | Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists. |
| Inhalation: | Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. |
| Ingestion: | Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel. |
| SECTION 5: Fire Fighting Measures | |
|---|---|
| Flash Point: | -7°F |
| Autoignition Temperature: | no data available |
| Explosion Limits: | LEL (1.7%) UEL (7.7%) |
| Extinguishing Medium: | Vermiculite, sand, dry chemical. Use no water |
| Special Fire Fighting Procedures: | If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self- contained breathing apparatus and full protective clothing. |
| Hazardous Combustion and Decomposion Products: | If involved in a fire this material may emit irritating zinc fume. |
| Unusual Fire or Explosion Hazards: | Extremely flammable. If hexane is allowed to evaporate, material becomes pyrophoric. |
| SECTION 6: Accidental Release Measures | |
|---|---|
| Spill and Leak Procedures: | Material may ignite spontaneously in air. Burning material may release toxic fumes. Leave the area unless fitted with a self-contained breathing apparatus. Smother fire with dry powder. Do not use water. |
| SECTION 7: Handling and Storage | |
|---|---|
| Handling and Storage: | Store in a steel cylinder under dry argon or nitrogen. Transfer using metal, not plastic materials. Expect fire when disassembling used piping. Do not use flammable solvents to clean out piping. |
| SECTION 8: Exposure Controls and Personal Protection | |
|---|---|
| Eye Protection: | Always wear approved safety glasses when handling a chemical substance in the laboratory. |
| Skin Protection: | Wear protective clothing and gloves. |
| Ventilation: | This product must only be handled in an efficient fume hood. |
| Respirator: | If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134. |
| Additional Protection: | Wear full face shield, lab apron and suitable gloves. |
| SECTION 9: Physical and Chemical Properties | |
|---|---|
| Color and Form: | colorless liq. |
| Molecular Weight: | 123.49 |
| Melting Point: | no data |
| Boiling Point: | no data |
| Vapor Pressure: | no data |
| Specific Gravity: | no data |
| Odor: | pungent odor |
| Solubility in Water: | reacts violently with water |
| SECTION 10: Stability and Reactivity | |
|---|---|
| Stability: | air and moisture-sensitive liquid |
| Hazardous Polymerization: | no hazardous polymerization |
| Conditions to Avoid: | Contact with air and moisture. |
| Incompatibility: | Water, alcohols, carbonyl compounds, mineral acids, oxidizing agents, air, and chlorinated hydrocarbons. |
| Decomposition Products: | carbon monoxide, carbon dioxide, organic fumes, and zinc oxide. |
| SECTION 11: Toxicological Information | |
|---|---|
| RTECS Data: | No information available on title compound. For hexane--Standard Draize Test(rabbit); 10mg (mild). Inhalation (human); TCLo: 190ppm/8W. Oral (rat); LD50: 28710mg/kg. Inhalation (rat); LC50: 48000ppm/4H. Intraperitoneal (rat); LDLo: 9100mg/kg. Intravenous (mouse); LDLo:831mg/kg. Inhalation (rat); TCLo: 2000ppm/12H/24W-I. TDLo: 38g/Kg oral (mouse) fetotoxicity; TcLo: 10,000 ppm/7H Inhal (rat) reproductive, behavioral, newborn; TcLo: 1000 ppm/6H Inhal (rat) reproductive, newborn, wt. loss; TcLo: 5000 ppm/20H Inhal (rat) reproductive, newborn, wt. loss, fetotoxicity |
| Carcinogenic Effects: | No data available |
| Mutagenic Effects: | Hexane: Possible mutagen |
| Tetratogenic Effects: | Hexane: Possible reproductive effector |
| SECTION 12: Ecological Information | |
|---|---|
| Ecological Information: | Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. |
| SECTION 13: Disposal Considerations | |
|---|---|
| Disposal: | Dispose of according to local, state and federal regulations. |
| SECTION 14: Transportation | |
|---|---|
| Shipping Name (CFR): | Flammable liquids, N.O.S. |
| Hazard Class (CFR): | 3 |
| Additional Hazard Class (CFR): | NA |
| Packaging Group (CFR): | I |
| UN ID Number (CFR): | UN# 1993 |
| Shipping Name (IATA): | Flammable liquids, N.O.S. |
| Hazard Class (IATA): | 3 |
| Additional Hazard Class (IATA): | NA |
| Packaging Group (IATA): | I |
| UN ID Number (IATA): | UN# 1993 |
| SECTION 15: Regulatory Information | |
|---|---|
| TSCA: | Listed in the TSCA inventory. |
| SARA (Title 313): | Title compound: See category N982 for reporting. |
| Second Ingredient: | Hexane: listed on TSCA. Reportable under SARA 313. |
| Third Ingredient: | None |
| SECTION 16: Other Information | |
|---|---|
| Disclaimer: | The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information. |
| Preparation Date: | 5/13/2002 |
| Revision Date: | 9/27/2011 |