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CAS Number: 135707-05-0
Product Catalog

29-2930
Copper Trimethylphosphine(hexafluoroacetylacetonato)copper(I), min. 98%
CAS Number: 135707-05-0
MDL Number: MFCD00145461
Molecular Formula: C8H10CuF6O2P
Molecular Weight: 346.68
Chemical Formula: Cu(CF3COCHCOCF3)P(CH3)3
Color and Form: orange xtl.
Note:  

Stability: air sensitive

Physical Characteristics: melting point 65°C, boiling point (subl. 33°C/10mm)

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SECTION 1: Product Identification
Chemical Name: Trimethylphosphine(hexafluoroacetylacetonato)copper (I), min. 98%
Product Number: 29-2930
CAS Registry Number: 135707-05-0
Formula: Cu(CF3COCHCOCF3)P(CH3)3
EINECS Number: none
Chemical Family: metal fluorobeta-diketonate complexes
Synonym: Trimethylphosphinecopper (I) hexafluoroacetylacetonate
SECTION 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title Compound 135707-05-0 100 1mg/m3 (as Cu) 1mg/m3 (as Cu)
SECTION 3: Hazards Identification
Emergency Overview: Copper compounds are irritating to the skin, eyes and respiratory tract. If inhaled or swallowed this compound may cause fluoride poisoning. Early symptoms include nausea, vomiting, diarrhea, and weakness
Primary Routes of Exposure: Ingestion, inhalation, skin, eyes
Eye Contact: Causes irritation and serious eye damage. Effects may not immediately appear.
Skin Contact: Causes irritation, with redness and pain. Effects may not appear immediately.
Inhalation: Inhalation causes severe irritation to the respiratory tract, causing coughing, sore throat, and labored breathing.
Ingestion: Ingestion may lead to dizziness, abdominal cramps, vomiting, bloody diarrhea, weakness, convulsions, and fluoride poisoning.
Acute Health Effects: Irritating to skin, eyes and respiratory tract. Ingestion of copper and fluoride compounds may lead to nausea, vomiting, diarrhea, exhaustion, anemia, convulsions, respiratory paralysis, and coma.
Chronic Health Effects: The dust of copper compounds may cause metal fume fever, hemolysis of the red blood cells and injury to the liver, lungs, kidneys and pancreas. Chronic fluoride poisoning can cause severe bone changes, loss of weight, and dental defects.
NTP: No
IARC: No
OSHA: No
SECTION 4: First Aid Measures
Eye Exposure: Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention.
Skin Exposure: Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists.
Inhalation: Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Ingestion: Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel.
SECTION 5: Fire Fighting Measures
Flash Point: not applicable
Autoignition Temperature: none
Explosion Limits: none
Extinguishing Medium: carbon dioxide, foam or dry powder
Special Fire Fighting Procedures: If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self- contained breathing apparatus and full protective clothing.
Hazardous Combustion and Decomposion Products: Combustible material. If involved in a fire this material may emit toxic and corrosive fumes.
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.
SECTION 6: Accidental Release Measures
Spill and Leak Procedures: Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and swept up.
SECTION 7: Handling and Storage
Handling and Storage: Store material in a cool, dry place in a tightly sealed container under an inert atmosphere of nitrogen or argon.
SECTION 8: Exposure Controls and Personal Protection
Eye Protection: Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection: Wear protective clothing and gloves.
Ventilation: Material may form a fine dust. If possible, handle the material in an efficient fume hood.
Respirator: If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Additional Protection: No additional protection required.
SECTION 9: Physical and Chemical Properties
Color and Form: orange xtl.
Molecular Weight: 346.68
Melting Point: 65°C
Boiling Point: (subl. 33°C/10mm)
Vapor Pressure: no data
Specific Gravity: no data
Odor: none
Solubility in Water: insoluble
SECTION 10: Stability and Reactivity
Stability: air-sensitive solid
Hazardous Polymerization: no hazardous polymerization
Conditions to Avoid: none
Incompatibility: oxidizing agents and active metals
Decomposition Products: organic fumes, hydrogen fluoride, carbon monoxide, carbon dioxide.
SECTION 11: Toxicological Information
RTECS Data: No specific information available on this product.
Carcinogenic Effects: No data
Mutagenic Effects: No data
Tetratogenic Effects: No data
SECTION 12: Ecological Information
Ecological Information: No information available
SECTION 13: Disposal Considerations
Disposal: Dispose of according to local, state and federal regulations.
SECTION 14: Transportation
Shipping Name (CFR): Non-hazardous
Hazard Class (CFR): NA
Additional Hazard Class (CFR): NA
Packaging Group (CFR): NA
UN ID Number (CFR): NA
Shipping Name (IATA): Non-hazardous
Hazard Class (IATA): NA
Additional Hazard Class (IATA): NA
Packaging Group (IATA): NA
UN ID Number (IATA): NA
SECTION 15: Regulatory Information
TSCA: Not listed in the TSCA inventory.
SARA (Title 313): Title compound: See category N100 for reporting.
Second Ingredient: None
Third Ingredient: None
SECTION 16: Other Information
Disclaimer: The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information.
Preparation Date: 3/29/2002
Revision Date: 12/13/2011

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