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CAS Number: 57197-55-4

28-0086
Nickel › Bis(i-propylcyclopentadienyl)nickel, min. 98%
CAS Number: 57197-55-4
MDL Number: MFCD01862459
Molecular Formula: C16H22Ni
Molecular Weight: 273.04
Chemical Formula: [(C3H7)C5H4]2Ni
Color and Form: green liq.
Note:  

Stability: air sensitive, store cold

Safety: Hazardous

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SECTION 1: Product Identification
Chemical Name: Bis(i-propylcyclopentadienyl)nickel, min. 98%
Product Number: 28-0086
CAS Registry Number: 57197-55-4
Formula: [(C3H7)C5H4]2Ni
EINECS Number: none
Chemical Family: organometallic complexes
Synonym: Bis(1-methylethylcyclopentadienyl)nickel (II)
SECTION 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title compound 57197-55-4 100 0.2mg/m3 (as Ni) 1mg/m3 (as Ni)
SECTION 3: Hazards Identification
Emergency Overview: Irritating to skin, eyes and mucous membranes. Nickel and certain nickel compounds may cause cancer.
Primary Routes of Exposure: Ingestion, eyes
Eye Contact: Causes slight to mild irritation of the eyes
Skin Contact: Causes slight to mild irritation of the skin.
Inhalation: Irritating to the nose, mucous membranes and respiratory tract.
Ingestion: Ingestion may lead to vomiting, and diarrhea.
Acute Health Effects: Irritating to skin, eyes and respiratory tract.
Chronic Health Effects: No information available on long-term chronic effects. May cause cancer.
NTP: Yes
IARC: Yes
OSHA: No
SECTION 4: First Aid Measures
Eye Exposure: Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention.
Skin Exposure: Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists.
Inhalation: Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Ingestion: Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel.
SECTION 5: Fire Fighting Measures
Flash Point: none
Autoignition Temperature: none
Explosion Limits: none
Extinguishing Medium: carbon dioxide, foam or dry powder
Special Fire Fighting Procedures: If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self- contained breathing apparatus and full protective clothing.
Hazardous Combustion and Decomposion Products: If involved in a fire this material may emit irritating fumes.
Unusual Fire or Explosion Hazards: Highly flammable. Formation of explosive air/vapor mixtures is possible.
SECTION 6: Accidental Release Measures
Spill and Leak Procedures: Small spills can be absorbed into vermiculite or other chemical adsorbent and swept up.
SECTION 7: Handling and Storage
Handling and Storage: Store in a cool, dry area away from heat and direct sunlight. This product may degrade on contact with air. Store under an inert atmosphere of nitrogen or argon.
SECTION 8: Exposure Controls and Personal Protection
Eye Protection: Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection: Wear protective clothing and gloves.
Ventilation: If possible, handle the material in an efficient fume hood.
Respirator: If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Additional Protection: No additional protection required.
SECTION 9: Physical and Chemical Properties
Color and Form: green liquid
Molecular Weight: 273.04
Melting Point: no data
Boiling Point: no data
Vapor Pressure: no data
Specific Gravity: no data
Odor: none
Solubility in Water: insoluble
SECTION 10: Stability and Reactivity
Stability: air-sensitive liquid
Hazardous Polymerization: none
Conditions to Avoid: contact with strong oxidizing agents
Incompatibility: strong oxidizing agents
Decomposition Products: carbon dioxide, carbon monoxide, organic fumes, and nickel oxide.
SECTION 11: Toxicological Information
RTECS Data: No information available in RTECS.
Carcinogenic Effects: Nickel and certain nickel compounds are anticipated to be carcinogens.
Mutagenic Effects: No data available
Tetratogenic Effects: No data available
SECTION 12: Ecological Information
Ecological Information: No information available
SECTION 13: Disposal Considerations
Disposal: Dispose of according to local, state and federal regulations.
SECTION 14: Transportation
Shipping Name (CFR): Flammable liquids, N.O.S.
Hazard Class (CFR): 3
Additional Hazard Class (CFR): NA
Packaging Group (CFR): II
UN ID Number (CFR): UN #1993
Shipping Name (IATA): Flammable liquid, N.O.S.
Hazard Class (IATA): 3
Additional Hazard Class (IATA): NA
Packaging Group (IATA): II
UN ID Number (IATA): UN# 1993
SECTION 15: Regulatory Information
TSCA: not listed on the TSCA inventory
SARA (Title 313): See Category Code N495 for reporting.
Second Ingredient: none
Third Ingredient: none
SECTION 16: Other Information
Disclaimer: The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information.
Preparation Date: 2/18/2000
Revision Date: 12/16/2011

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