Product Catalog
CAS Number: 13463-40-6

26-2801

Iron › Iron pentacarbonyl, 99.5% (Sure/Seal™ bottle)

Stability: air sensitive, store cold

Safety: Hazardous

Physical Characteristics: melting point -20°C, boiling point 103°C, flash point 5°F, density 1.490

Transportation: Boat, truck. See MSDS sheet.

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SECTION 1: Product Identification
Chemical Name:	Iron pentacarbonyl, 99.5% (Sure/Seal� bottle)
Product Number:	26-2801
CAS Registry Number:	13463-40-6
Formula:	Fe(CO)5
EINECS Number:	236-670-8
Chemical Family:	metal carbonyl complexes
Synonym:	Pentacarbonyliron

SECTION 2: Composition and Information on Ingredients
Ingredient	CAS Number	Percent	ACGIH (TWA)	OSHA (PEL)
Title compound	13463-40-6	100	0.1ppm	no data

SECTION 3: Hazards Identification
Emergency Overview:	Extremely flammable liquid. Toxic in contact with skin. Very toxic by inhalation and if swallowed.
Primary Routes of Exposure:	Ingestion, inhalation, skin contact
Eye Contact:	May cause mild to severe irritation of the eyes.
Skin Contact:	May cause irritation of the skin.
Inhalation:	Severe poison. Inhalation or skin absorption may be fatal.
Ingestion:	Toxic if swallowed. May cause dizziness, nausea, vomiting and pain.
Acute Health Effects:	Early symptoms of a toxic dose include headache, vomiting, nausea and breathlessness. Late symptoms include pain in the chest, a dry, hard cough and bluish coloration of the face and ears.
Chronic Health Effects:	High or repeated exposures may cause damage to the heart, muscles, liver and kidneys.
NTP:	No
IARC:	No
OSHA:	No

SECTION 4: First Aid Measures
Eye Exposure:	Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention.
Skin Exposure:	Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists.
Inhalation:	Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Ingestion:	Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:	5°F
Autoignition Temperature:	no data
Explosion Limits:	no data
Extinguishing Medium:	carbon dioxide, dry powder or foam
Special Fire Fighting Procedures:	If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus and full protective clothing.
Hazardous Combustion and Decomposion Products:	carbon monoxide, carbon dioxide, fine iron oxide dust
Unusual Fire or Explosion Hazards:	Extremely flammable. Material may ignite spontaneously on prolonged contact with air.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:	If iron carbonyl is spilled all personnel must be immediately evacuated and the area sealed off. Ventilation should be available. If entry into the area is required, personnel should be fitted with a self-contained breathing apparatus. Remove all ignition sources. Absorb spill into vermiculite or other suitable adsorbent.

SECTION 7: Handling and Storage
Handling and Storage:	Store in a cool, dry, well-ventilated area away from heat and direct sunlight. Keep containers tightly sealed. To insure maximum shelf life, the material should be stored at 0-10�C. Always handle material in an efficient fume hood.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:	Always wear approved safety glasses. When handling this substance, wear a face shield as added protection.
Skin Protection:	Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.
Ventilation:	It is imperative that this product is handled in an efficient fume hood.
Respirator:	If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Additional Protection:	No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:	orange liquid
Molecular Weight:	195.90
Melting Point:	no data available
Boiling Point:	103°C
Vapor Pressure:	40mm(30.3°C)
Specific Gravity:	1.490
Odor:	musty odor
Solubility in Water:	insoluble

SECTION 10: Stability and Reactivity
Stability:	air sensitive(store cold)
Hazardous Polymerization:	no hazardous polymerization
Conditions to Avoid:	prolonged contact with air. Heat and light
Incompatibility:	oxidizing agents, halogens, active metals, air(pyrophoric), carbon tetrachloride and powdered metallic oxides.
Decomposition Products:	carbon dioxide, carbon monoxide, organic fumes and iron oxide

SECTION 11: Toxicological Information
RTECS Data:	Oral (rat); LD50: 25mg/kg. Inhalation (rat); LC50: 10ppm/4H. Oral (mouse); LD50: 62mg/kg. Inhalation (mouse); LC50: 2190mg/m3/30M. Intraperitoneal (mouse); LD50: 60mg/kg. Oral (cat); LD50: 100mg/kg. Oral (rabbit); LD50: 12mg/kg. Inhalation (rabbit); LDLo: 250ppm/45M. Administration onto the skin (rabbit); LD50: 56mg/kg. Inhalation (guinea pig); LCLo: 140ppm/30M. Inhalation (rat); TCLo: 15ppm/6H/2D-I.
Carcinogenic Effects:	No data
Mutagenic Effects:	No data
Tetratogenic Effects:	No data

SECTION 12: Ecological Information
Ecological Information:	No information available

SECTION 13: Disposal Considerations
Disposal:	Dispose of according to local, state and federal regulations. For purposes of shipping waste material, see section 14 in this document on transportation.

SECTION 14: Transportation
Shipping Name (CFR):	Iron pentacarbonyl
Hazard Class (CFR):	6.1 (inhalation hazard)
Additional Hazard Class (CFR):	3
Packaging Group (CFR):	I
UN ID Number (CFR):	UN# 1994
Shipping Name (IATA):	Prohibited
Hazard Class (IATA):	NA
Additional Hazard Class (IATA):	NA
Packaging Group (IATA):	NA
UN ID Number (IATA):	UN# 1994

SECTION 15: Regulatory Information
TSCA:	Listed in the TSCA inventory
SARA (Title 313):	Reportable under SARA Title 313.
Second Ingredient:	none
Third Ingredient:	none

SECTION 16: Other Information
Disclaimer:	The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information.
Preparation Date:	10/10/2005
Revision Date:	12/16/2011