CAS Number: 3087-36-3
Product Catalog

22-2209

Titanium › Titanium(IV) ethoxide (99.99%-Ti) PURATREM

Stability: moisture sensitive

Safety: Hazardous

Physical Characteristics: density 1.088, melting point 54°C, boiling point 138°C/5mm, flash point 84°F

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SECTION 1: Product Identification
Chemical Name:	Titanium (IV) ethoxide (99.99%-Ti) PURATREM
Product Number:	22-2209
CAS Registry Number:	3087-36-3
Formula:	Ti(OC2H5)4
EINECS Number:	221-410-8
Chemical Family:	metal alkoxide
Synonym:	Titanium ethylate, Tetraethyoxytitanium

SECTION 2: Composition and Information on Ingredients
Ingredient	CAS Number	Percent	ACGIH (TWA)	OSHA (PEL)
Title Compound	3087-36-3	100	no data	no data

SECTION 3: Hazards Identification
Emergency Overview:	The liquid irritates the skin, eyes, and respiratory system. Moisture will produce ethanol vapor which may cause drowsiness.
Primary Routes of Exposure:	Inhalation, ingestion, contact with skin and eyes.
Eye Contact:	The liquid and ethanol hydrolysis product causes moderate irritation of the eyes.
Skin Contact:	Dehydrating agent. Liquid causes mild irritation of the skin.
Inhalation:	Liquid causes moderate irritation to the upper respiratory tract. Ethanol vapor may cause dizziness and drowsiness
Ingestion:	Ingestion may cause gastrointestinal distress, nausea, vomiting and headache.
Acute Health Effects:	The product is a mild irritant. ethanol is a skin and eye irritant. Exposure may cause impairment of coordination and reaction time.
Chronic Health Effects:	No data is available for this product. Prolonged exposure to ethanol vapors may be harmful to nerves and liver.
NTP:	No
IARC:	No
OSHA:	No

SECTION 4: First Aid Measures
Eye Exposure:	Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention.
Skin Exposure:	Wash the affected area with soap and water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists.
Inhalation:	Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Ingestion:	Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious).

SECTION 5: Fire Fighting Measures
Flash Point:	84°F
Autoignition Temperature:	no data
Explosion Limits:	no data
Extinguishing Medium:	carbon dioxide, dry powder or foam
Special Fire Fighting Procedures:	If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus and full protective clothing.
Hazardous Combustion and Decomposion Products:	If involved in a fire this material may emit toxic organic fumes.
Unusual Fire or Explosion Hazards:	Flammable. Formation of explosive air/ vapor mixtures is possible.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:	Eliminate all ignition sources. Avoid contact with water. Small spills may be adsorbed into diatomaceous earth, sand, or other suitable adsorbent, and swept up.

SECTION 7: Handling and Storage
Handling and Storage:	Store in a tightly sealed container in a cool dry place. If container is left open, product may adsorb moisture and carbon dioxide from the atmosphere and release methanol vapor.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:	Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:	Wear protective clothing and gloves.
Ventilation:	Material may form a vapor upon exposure to air. if possible, handle the material in an efficient fume hood.
Respirator:	If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Additional Protection:	No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:	xtl. to pale orange liq.
Molecular Weight:	228.14
Melting Point:	54°C
Boiling Point:	138°C/5mm
Vapor Pressure:	no data
Specific Gravity:	no data
Odor:	slight alcohol odor
Solubility in Water:	reacts with water

SECTION 10: Stability and Reactivity
Stability:	moisture sensitive
Hazardous Polymerization:	no hazardous polymerization
Conditions to Avoid:	Keep away from moisture, heat and ignition sources including open flame and electrostatic discharge.
Incompatibility:	water, mineral acids, halogens and oxidizing agents
Decomposition Products:	Carbon dioxide, carbon monoxide, organic vapors, soot, and metal oxides and carbonates.

SECTION 11: Toxicological Information
RTECS Data:	No information available in the RTECS files.
Carcinogenic Effects:	No data available
Mutagenic Effects:	No data available
Tetratogenic Effects:	No data available

SECTION 12: Ecological Information
Ecological Information:	No information available

SECTION 13: Disposal Considerations
Disposal:	Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):	Flammable liquids, N.O.S.
Hazard Class (CFR):	3
Additional Hazard Class (CFR):	NA
Packaging Group (CFR):	III
UN ID Number (CFR):	UN# 1993
Shipping Name (IATA):	Flammable liquid, N.O.S.
Hazard Class (IATA):	3
Additional Hazard Class (IATA):	NA
Packaging Group (IATA):	III
UN ID Number (IATA):	UN# 1993

SECTION 15: Regulatory Information
TSCA:	Listed in the TSCA inventory.
SARA (Title 313):	Not reportable under SARA section 313.
Second Ingredient:	none
Third Ingredient:	none

SECTION 16: Other Information
Disclaimer:	The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information.
Preparation Date:	8/05/2001
Revision Date:	12/14/2011