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CAS Number: 603-35-0
Product Catalog

15-6700
Phosphorus Triphenylphosphine, 99%
CAS Number: 603-35-0
MDL Number: MFCD00003043
Molecular Formula: C18H15P
Molecular Weight: 262.28
Chemical Formula: (C6H5)3P
Color and Form: white xtl.
Note:  

Physical Characteristics: melting point 79°C, boiling point 360°C, flash point 359°F

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SECTION 1: Product Identification
Chemical Name: Triphenylphosphine, 99%
Product Number: 15-6700
CAS Registry Number: 603-35-0
Formula: (C6H5)3P
EINECS Number: 210-036-0
Chemical Family: organophosphine ligand
Synonym: Triphenylphosphane, Triphenylphosphorus
SECTION 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title compound 603-35-0 100 no data no data
SECTION 3: Hazards Identification
Emergency Overview: Harmful if swallowed. Irritating to skin, eyes and respiratory tract. May cause sensitization by skin contact.
Primary Routes of Exposure: Ingestion, inhalation
Eye Contact: Causes slight to mild irritation of the eyes.
Skin Contact: Causes slight to mild irritation of the skin. May cause sensitization by skin contact.
Inhalation: Irritating to the nose, mucous membranes and respiratory tract.
Ingestion: Harmful if swallowed. Based on animal studies ingestion may lead to somnolence, ataxia, and convulsions. May cause vomiting and diarrhea.
Acute Health Effects: Harmful if swallowed. Irritating to skin, eyes and respiratory tract. May cause sensitization by skin contact.
Chronic Health Effects: Studies indicate that prolonged exposure can lead to nervous system injury, leg weakness, tremors, loss of muscle coordination and altered reflexes.
NTP: No
IARC: No
OSHA: No
SECTION 4: First Aid Measures
Eye Exposure: Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention.
Skin Exposure: Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists.
Inhalation: Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Ingestion: Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel.
SECTION 5: Fire Fighting Measures
Flash Point: 180°C
Autoignition Temperature: none
Explosion Limits: none
Extinguishing Medium: carbon dioxide, dry powder or foam
Special Fire Fighting Procedures: If this material is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus and full protective clothing.
Hazardous Combustion and Decomposion Products: If involved in a fire this material may emit toxic organic fumes.
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.
SECTION 6: Accidental Release Measures
Spill and Leak Procedures: Small spills can be mixed with vermiculite or sodium carbonate and swept up.
SECTION 7: Handling and Storage
Handling and Storage: Store in a tightly sealed container. Keep away from heat and direct sunlight.
SECTION 8: Exposure Controls and Personal Protection
Eye Protection: Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection: Wear protective clothing and gloves.
Ventilation: Material may form a fine dust. If possible, handle the material in an efficient fume hood.
Respirator: If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Additional Protection: No additional protection required.
SECTION 9: Physical and Chemical Properties
Color and Form: white flakes
Molecular Weight: 262.28
Melting Point: 79°C
Boiling Point: 360°C
Vapor Pressure: no data
Specific Gravity: 1.2
Odor: slight odor
Solubility in Water: insoluble
SECTION 10: Stability and Reactivity
Stability: air and moisture-stable solid
Hazardous Polymerization: none
Conditions to Avoid: contact with strong oxidizing agents
Incompatibility: strong oxidizing agents, halogens
Decomposition Products: carbon dioxide, carbon monoxide, phosphorus pentoxide, and organic fumes.
SECTION 11: Toxicological Information
RTECS Data: Administration onto the skin (rabbit); Standard Draize test:500 mg/24H [mild]. Administration into the eye (rabbit); Standard Draize test:500 mg/24H [mild]. Oral (rat); LD50:700 mg/kg. Inhalation (rat); LC50:1135 ppm/4H. Intramuscular (rat); LD50:1500 mg/kg. Oral (mouse); LD50:1 gm/kg. Subcutaneous (mouse); LD50:3 gm/kg. Oral (dog); LD50:>500 gm/kg. Administration onto the skin (rabbit); LD50:>5 gm/kg. Oral (chicken); LDLo:9 gm/kg. Oral (dog); TDLo:950 mg/kg/14D-I. Oral (dog); TDLo:525 mg/kg/21D-I. Inhalation (dog); TDLo:94500 ug/m3/6H/4W-I.
Carcinogenic Effects: No data available
Mutagenic Effects: No data available
Tetratogenic Effects: No data available
SECTION 12: Ecological Information
Ecological Information: Avoid release to the environment. Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment.
SECTION 13: Disposal Considerations
Disposal: Dispose of according to local, state and federal regulations.
SECTION 14: Transportation
Shipping Name (CFR): Non-hazardous
Hazard Class (CFR): NA
Additional Hazard Class (CFR): NA
Packaging Group (CFR): NA
UN ID Number (CFR): NA
Shipping Name (IATA): Non-hazardous
Hazard Class (IATA): NA
Additional Hazard Class (IATA): NA
Packaging Group (IATA): NA
UN ID Number (IATA): NA
SECTION 15: Regulatory Information
TSCA: listed on the TSCA inventory
SARA (Title 313): not reportable under SARA Title (313)
Second Ingredient: none
Third Ingredient: none
SECTION 16: Other Information
Disclaimer: The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information.
Preparation Date: 12/02/1999
Revision Date: 8/17/2011

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