| CAS Number: | 824-72-6 |
| MDL Number: | MFCD00002070 |
| Molecular Formula: | C6H5Cl2OP |
| Molecular Weight: | 194.99 |
| Chemical Formula: | C6H5P(O)Cl2 |
| Color and Form: | colorless to light yellow liq. |
| Note: |
Safety: Hazardous
Physical Characteristics: melting point 3°C, boiling point 258°C, flash point >230°F, density 1.394 (25°C)
| SECTION 1: Product Identification | |
|---|---|
| Chemical Name: | Phenyldichlorophosphine oxide, min. 94% |
| Product Number: | 15-4158 |
| CAS Registry Number: | 824-72-6 |
| Formula: | C6H5P(O)Cl2 |
| EINECS Number: | 212-534-3 |
| Chemical Family: | organophosphorus compound |
| Synonym: | benzenedichlorophosphine, Dichlorophenylphosphine |
| SECTION 2: Composition and Information on Ingredients | ||||
|---|---|---|---|---|
| Ingredient | CAS Number | Percent | ACGIH (TWA) | OSHA (PEL) |
| Title Compound | 824-72-6 | 100 | no data | no data |
| SECTION 3: Hazards Identification | |
|---|---|
| Emergency Overview: | Material has a pungent odor. Inhalation of vapor may cause coughing, headache, and pulmonary edema. Very corrosive to eyes, skin, nose, and mucous membranes. |
| Primary Routes of Exposure: | Contact with skin and eyes. Inhalation of vapor. |
| Eye Contact: | Causes burns to the eyes. May cause blindness. |
| Skin Contact: | Causes burns to the skin. Hydrochloric acid hydrolysis product is a corrosive liquid or vapor. |
| Inhalation: | Inhalation of vapor may cause burning sensation, spasms, coughing, headache, chemical pneumonitis and pulmonary edema. |
| Ingestion: | Corrosive to mouth throat and stomach. May cause dizziness, nausea, vomiting, pain and stomach upset. |
| Acute Health Effects: | Material has a pungent odor. Inhalation of vapor may cause chemical pneumonitis and pulmonary edema. Contact of liquid or vapor with skin and eyes causes burns. |
| Chronic Health Effects: | No information available on long-term chronic effects. |
| NTP: | No |
| IARC: | No |
| OSHA: | No |
| SECTION 4: First Aid Measures | |
|---|---|
| Eye Exposure: | Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention. |
| Skin Exposure: | Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists. |
| Inhalation: | Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. |
| Ingestion: | Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel. |
| SECTION 5: Fire Fighting Measures | |
|---|---|
| Flash Point: | 400°F |
| Autoignition Temperature: | no data |
| Explosion Limits: | no data |
| Extinguishing Medium: | dry chemical, carbon dioxide, or flood with water. |
| Special Fire Fighting Procedures: | If this material is involved in a fire, fire fighters should be equipped with a NIOSH-approved positive pressure self-contained breathing and full protective clothing. |
| Hazardous Combustion and Decomposion Products: | In a fire this material may emit toxic organic fumes and vapors of phosphorus oxides and hydrogen chloride. |
| Unusual Fire or Explosion Hazards: | No unusual fire or explosion hazards. |
| SECTION 6: Accidental Release Measures | |
|---|---|
| Spill and Leak Procedures: | Small spills can be neutralized with powdered sodium bicarbonate, lime, or calcium carbonate and swept up. Large spills in areas not adequately ventilated will require an evacuation of site. Emergency response teams will require self-contained breathing apparatus. |
| SECTION 7: Handling and Storage | |
|---|---|
| Handling and Storage: | Store in a cool, dry, well-ventilated area. Keep containers tightly sealed. Transfer material under an inert atmosphere of nitrogen argon or very dry air. |
| SECTION 8: Exposure Controls and Personal Protection | |
|---|---|
| Eye Protection: | Always wear safety glasses. If pouring or transferring this substance wear a face shield for additional protection. |
| Skin Protection: | Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove. |
| Ventilation: | Material has a pungent odor. Always handle material in an efficient fume hood. |
| Respirator: | If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134 |
| Additional Protection: | No additional protection required. |
| SECTION 9: Physical and Chemical Properties | |
|---|---|
| Color and Form: | colorless to light yellow liq. |
| Molecular Weight: | 194.99 |
| Melting Point: | 3°C |
| Boiling Point: | 258°C |
| Vapor Pressure: | no data |
| Specific Gravity: | 1.394 (25°) |
| Odor: | sharp pungent odor |
| Solubility in Water: | reacts with water |
| SECTION 10: Stability and Reactivity | |
|---|---|
| Stability: | air stable, moisture sensitive |
| Hazardous Polymerization: | no hazardous polymerization |
| Conditions to Avoid: | contact with moisture |
| Incompatibility: | oxidizing agents, halogens and active metals |
| Decomposition Products: | Water: Hydrogen chloride and benzene phosphonic acid. Thermal: carbon oxides, organic vapors, phosphorous oxides |
| SECTION 11: Toxicological Information | |
|---|---|
| RTECS Data: | No information available in the RTECS files. |
| Carcinogenic Effects: | no information available |
| Mutagenic Effects: | no information available |
| Tetratogenic Effects: | no information available |
| SECTION 12: Ecological Information | |
|---|---|
| Ecological Information: | No information available |
| SECTION 13: Disposal Considerations | |
|---|---|
| Disposal: | Dispose of according to federal, state, and local regulations. |
| SECTION 14: Transportation | |
|---|---|
| Shipping Name (CFR): | Corrosive liquids, N.O.S. |
| Hazard Class (CFR): | 8 |
| Additional Hazard Class (CFR): | NA |
| Packaging Group (CFR): | II |
| UN ID Number (CFR): | UN# 1760 |
| Shipping Name (IATA): | Corrosive liquid, N.O.S. |
| Hazard Class (IATA): | 8 |
| Additional Hazard Class (IATA): | NA |
| Packaging Group (IATA): | II |
| UN ID Number (IATA): | UN# 1760 |
| SECTION 15: Regulatory Information | |
|---|---|
| TSCA: | Listed in the TSCA inventory. |
| SARA (Title 313): | Title compound not listed. |
| Second Ingredient: | none |
| Third Ingredient: | none |
| SECTION 16: Other Information | |
|---|---|
| Disclaimer: | The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information. |
| Preparation Date: | 5/14/2001 |
| Revision Date: | 12/16/2011 |