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CAS Number: 1017-60-3
Product Catalog

15-1820
Phosphorus › Di-p-tolylphosphine, 99%
CAS Number: 1017-60-3
MDL Number: MFCD01630843
Molecular Formula: C14H15P
Molecular Weight: 214.25
Chemical Formula: (CH3C6H4)2PH
Color and Form: colorless liq.
Note:  

Safety: Hazardous, pyrophoric

Transportation: Boat, truck. See MSDS sheet. Alternative for air shipment see 15-1819

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Download This MSDS
SECTION 1: Product Identification
Chemical Name: Di-p-tolylphosphine, 99%
Product Number: 15-1820
CAS Registry Number: 1017-60-3
Formula: (CH3C6H4)2PH
EINECS Number: none
Chemical Family: organophosphine ligand
Synonym: none
SECTION 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title Compound 1017-60-3 100 no data no data
SECTION 3: Hazards Identification
Emergency Overview: Harmful by inhalation, in contact with skin and if swallowed. May ignite spontaneously on contact with air. Contact with skin may result in severe chemical burns.
Primary Routes of Exposure: Skin and inhalation
Eye Contact: May cause mild to severe irritation of the eyes.
Skin Contact: Harmful in contact with skin. May cause mild irritation of the skin, or thermal burns if ignited.
Inhalation: Harmful by inhalation. Inhalation may lead to dizziness and headaches.
Ingestion: Harmful if swallowed. Ingestion is an unlikely mode of entry as the material is pyrophoric and has a noxious odor.
Acute Health Effects: Harmful by inhalation, in contact with skin and if swallowed.
Chronic Health Effects: No information available on long term exposure to this material.
NTP: No
IARC: No
OSHA: No
SECTION 4: First Aid Measures
Eye Exposure: Immediately flush the eyes with copious amounts of water for at least 15 minutes. A victim will need assistance in keeping their eye lids open. Get immediate medical attention.
Skin Exposure: Wash the affected area immediately with water. Remove contaminated clothing if necessary. Seek medical assistance if irritation persists.
Inhalation: Remove victim to fresh air immediately. Keep the victim lying down and warm. Give oxygen as soon as possible. If shock occurs, respond with appropriate first aid. Transport the victim to a hospital.
Ingestion: Seek medical attention immediately. Keep the victim calm. Give water to dilute the toxin (only if conscious). Induce vomiting only if directed by medical personnel.
SECTION 5: Fire Fighting Measures
Flash Point: no data
Autoignition Temperature: Pyrophoric
Explosion Limits: Pyrophoric
Extinguishing Medium: carbon dioxide, dry powder or foam
Special Fire Fighting Procedures: The pyrophoric liquid may reignite. Fire fighters should be equipped with an approved positive pressure self-contained breathing apparatus and full protective clothing.
Hazardous Combustion and Decomposion Products: If involved in a fire this material may emit toxic organic fumes and vapors of phosphorus pentoxide.
Unusual Fire or Explosion Hazards: Spontaneously flammable in air, especially in contact with organic matter such as paper or cloth.
SECTION 6: Accidental Release Measures
Spill and Leak Procedures: 'The material may ignite spontaneously in air. Avoid static discharge. Burning material may release toxic fumes. In case of poor ventilation, leave the area unless fitted with a self-contained breathing apparatus. Small spills can be mixed with ground limestone, sodium bicarbonate, or other suitable absorbents, swept up, and held in a closed metal can.
SECTION 7: Handling and Storage
Handling and Storage: Store in a tightly sealed container under an inert atmosphere of nitrogen or argon. Keep away from heat. Material should be transferred under an inert atmosphere of nitrogen or argon in a efficient fume hood. Fire may occur in emptied container and transfer lines.
SECTION 8: Exposure Controls and Personal Protection
Eye Protection: Always wear approved safety glasses. When handling this substance wear a face shield as added protection.
Skin Protection: Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.
Ventilation: Material has a pungent odor. Always handle material in an efficient fume hood.
Respirator: If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance 29 CFR 1910.134.
Additional Protection: Wear a full face shield, flame resistant lab apron and suitable gloves.
SECTION 9: Physical and Chemical Properties
Color and Form: colorless liq.
Molecular Weight: 214.25
Melting Point: no data
Boiling Point: no data
Vapor Pressure: no data
Specific Gravity: no data
Odor: pungent and noxious odor
Solubility in Water: insoluble
SECTION 10: Stability and Reactivity
Stability: air-sensitive liquid - pyrophoric
Hazardous Polymerization: no hazardous polymerization
Conditions to Avoid: Contact with air. Material may spontaneously ignite, especially in the presence of organic matter such as paper or cloth.
Incompatibility: oxidizing agents, halogens, air (pyrophoric), halocarbons, sulfur.
Decomposition Products: carbon dioxide, carbon monoxide, organic vapors, and phosphorus pentoxide.
SECTION 11: Toxicological Information
RTECS Data: No information available in the RTECS files.
Carcinogenic Effects: No information available.
Mutagenic Effects: No information available.
Tetratogenic Effects: No information available.
SECTION 12: Ecological Information
Ecological Information: No information available.
SECTION 13: Disposal Considerations
Disposal: Dispose of this material according to local, state and federal regulations.
SECTION 14: Transportation
Shipping Name (CFR): Pyrophoric liquids, organic, N.O.S.
Hazard Class (CFR): 4.2
Additional Hazard Class (CFR): NA
Packaging Group (CFR): I
UN ID Number (CFR): UN# 2845
Shipping Name (IATA): Prohibited
Hazard Class (IATA): NA
Additional Hazard Class (IATA): NA
Packaging Group (IATA): NA
UN ID Number (IATA): NA
SECTION 15: Regulatory Information
TSCA: not listed on the TSCA inventory
SARA (Title 313): not regulated by SARA 313
Second Ingredient: none
Third Ingredient: none
SECTION 16: Other Information
Disclaimer: The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information.
Preparation Date: 10/28/1999
Revision Date: 7/29/2011

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