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CAS Number: 36042-94-1
Product Catalog

15-1815
Phosphorus Di-o-tolylchlorophosphine, min. 98%
CAS Number: 36042-94-1
MDL Number: MFCD04038733
Molecular Formula: C14H14ClP
Molecular Weight: 248.69
Chemical Formula: (CH3C6H4)2PCl
Color and Form: white solid to viscous liq.
Note:  

Stability: air sensitive, moisture sensitive

Safety: Hazardous

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SECTION 1: Product Identification
Chemical Name: Di-o-tolylchlorophosphine, min. 98%
Product Number: 15-1815
CAS Registry Number: 36042-94-1
Formula: (CH3C6H4)2PCl
EINECS Number: none
Chemical Family: organophosphine halide
Synonym: Di-o-tolylchlorophosphane
SECTION 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title compound 36042-94-1 100 no data no data
SECTION 3: Hazards Identification
Emergency Overview: Corrosive to skin, eyes and mucous membranes. Causes burns. Harmful by inhalation, in contact with skin and if swallowed.
Primary Routes of Exposure: Ingestion, inhalation, eyes, skin
Eye Contact: Corrosive to the eyes. Exposure can lead to permanent eye damage.
Skin Contact: Corrosive to skin. Contact can lead to redness, pain, blistering, ulceration, and scar formation.
Inhalation: Inhalation of vapor may cause burning sensation, spasms, coughing, headache, chemical pneumonitis and pulmonary edema.
Ingestion: Corrosive to mouth throat and stomach. May cause dizziness, nausea, vomiting, pain and stomach upset.
Acute Health Effects: Corrosive to skin, eyes and mucous membranes. Causes burns. Harmful by inhalation, in contact with skin and if swallowed.
Chronic Health Effects: No information on long-term chronic effects.
NTP: No
IARC: No
OSHA: No
SECTION 4: First Aid Measures
Eye Exposure: Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention.
Skin Exposure: Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists.
Inhalation: Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Ingestion: Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel.
SECTION 5: Fire Fighting Measures
Flash Point: no data
Autoignition Temperature: none
Explosion Limits: none
Extinguishing Medium: carbon dioxide, dry powder or foam.
Special Fire Fighting Procedures: Fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus and full protective clothing.
Hazardous Combustion and Decomposion Products: If involved in a fire this material may emit toxic organic fumes and vapors of phosphorus pentoxide.
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazard.
SECTION 6: Accidental Release Measures
Spill and Leak Procedures: Small spills can be mixed with vermiculite or other suitable absorbents. Spillage in areas not adequately ventilated will require an evacuation of site. Emergency response teams will require self-contained breathing apparatus.
SECTION 7: Handling and Storage
Handling and Storage: Material must be handled and stored under an inert atmosphere of nitrogen or argon.
SECTION 8: Exposure Controls and Personal Protection
Eye Protection: Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection: Wear protective gloves and clothing.
Ventilation: Handle the material in an efficient fume hood.
Respirator: If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Additional Protection: No additional protection required.
SECTION 9: Physical and Chemical Properties
Color and Form: white solid to viscous liquid
Molecular Weight: 248.69
Melting Point: no data
Boiling Point: no data
Vapor Pressure: no data
Specific Gravity: no data
Odor: sharp, acidic odor
Solubility in Water: reacts with water
SECTION 10: Stability and Reactivity
Stability: air and moisture sensitive liquid
Hazardous Polymerization: no hazardous polymerization
Conditions to Avoid: contact with air and moisture
Incompatibility: water, oxidizing agents, halogens and active metals.
Decomposition Products: carbon dioxide, carbon monoxide, hydrogen chloride, organic vapors, chlorinated hydrocarbons and phosphorus pentoxide.
SECTION 11: Toxicological Information
RTECS Data: No information available in the RTECS files.
Carcinogenic Effects: no data
Mutagenic Effects: no data
Tetratogenic Effects: no data
SECTION 12: Ecological Information
Ecological Information: No information available
SECTION 13: Disposal Considerations
Disposal: Dispose of according to federal, state, and local regulations.
SECTION 14: Transportation
Shipping Name (CFR): Corrosive liquids, N.O.S.
Hazard Class (CFR): 8
Additional Hazard Class (CFR): NA
Packaging Group (CFR): II
UN ID Number (CFR): UN# 1760
Shipping Name (IATA): Corrosive liquid, N.O.S.
Hazard Class (IATA): 8
Additional Hazard Class (IATA): NA
Packaging Group (IATA): II
UN ID Number (IATA): UN# 1760
SECTION 15: Regulatory Information
TSCA: Not listed in the TSCA inventory.
SARA (Title 313): Title compound not listed.
Second Ingredient: none
Third Ingredient: none
SECTION 16: Other Information
Disclaimer: The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information.
Preparation Date: 1/23/2004
Revision Date: 12/20/2011

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