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CAS Number: 1053657-14-9
Product Catalog
15-1812
Phosphorus › 2-(Di-i-propylphosphino)ethylamine, min. 97% (10 wt% in THF)| CAS Number: | 1053657-14-9 |
| MDL Number: | MFCD11044863 |
| Molecular Formula: | C8H20NP |
| Molecular Weight: | 161.23 |
| Chemical Formula: | (C3H7)2PCH2CH2NH2 |
| Color and Form: | pale yellow to colorless liq. |
| Note: |
Stability: air sensitive
Safety: Hazardous
| SECTION 1: Product Identification | |
|---|---|
| Chemical Name: | 2-(Di-i-propylphosphino)ethylamine, min. 97% (10 wt% in THF) |
| Product Number: | 15-1812 |
| CAS Registry Number: | 1053657-14-9 |
| Formula: | C8H20NP |
| EINECS Number: | none |
| Chemical Family: | aminophosphine ligand |
| Synonym: | 2-(Diisopropylphosphno)ethylamine |
| SECTION 2: Composition and Information on Ingredients | ||||
|---|---|---|---|---|
| Ingredient | CAS Number | Percent | ACGIH (TWA) | OSHA (PEL) |
| Title compound | 1053657-14-9 | 10 | no data | no data |
| THF | 109-99-9 | 90 | 50ppm | 590mg/m3 |
| SECTION 3: Hazards Identification | |
|---|---|
| Emergency Overview: | Harmful if swallowed. Inhalation may cause dizziness, headache and shortness of breath. Irritating to skin, eyes and respiratory tract. Possible risk of harm to the unborn child. |
| Primary Routes of Exposure: | Inhalation, skin, eyes |
| Eye Contact: | Causes moderate irritation of the eyes. |
| Skin Contact: | Causes moderate to severe irritation of the skin. |
| Inhalation: | Inhalation of vapors may cause coughing, chest pains, nausea, dizziness, headache, drowsiness and unconsciousness. |
| Ingestion: | Harmful if swallowed. THF can cause liver and kidney damage. Harmful if swallowed. |
| Acute Health Effects: | Inhalation of vapors induces drowsiness and may cause coughing, chest pains, difficulty in breathing, nausea, dizziness, headache and unconsciousness. Skin and eye contact results in irritation. |
| Chronic Health Effects: | Tetrahydrofuran is an eye and mucous membrane irritant and can cause liver and kidney damage. Possible risk of irreversible effects. |
| NTP: | No |
| IARC: | No |
| OSHA: | No |
| SECTION 4: First Aid Measures | |
|---|---|
| Eye Exposure: | Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention. |
| Skin Exposure: | Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists. |
| Inhalation: | Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. |
| Ingestion: | Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel. |
| SECTION 5: Fire Fighting Measures | |
|---|---|
| Flash Point: | 1°F (THF) |
| Autoignition Temperature: | 610°F (THF) |
| Explosion Limits: | 1.8%-11.8% (THF) |
| Extinguishing Medium: | carbon dioxide, dry powder or foam |
| Special Fire Fighting Procedures: | If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus and full protective clothing. |
| Hazardous Combustion and Decomposion Products: | If involved in a fire, this material may emit toxic organic fumes and corrosive phosphorus pentoxide dust. |
| Unusual Fire or Explosion Hazards: | Flammable liquid. Evolves flammable hydrogen gas with water. Hydrogen can ignite explosively. |
| SECTION 6: Accidental Release Measures | |
|---|---|
| Spill and Leak Procedures: | Eliminate all potential ignition sources. Small spills can be absorbed into vermiculite or other chemical adsorbent suitable for flammable materials. Sweep up the mixture and dispose of properly. |
| SECTION 7: Handling and Storage | |
|---|---|
| Handling and Storage: | Handle and store this material under an inert atmosphere of nitrogen or argon. Keep away from heat. |
| SECTION 8: Exposure Controls and Personal Protection | |
|---|---|
| Eye Protection: | Always wear approved safety glasses when handling a chemical substance in the laboratory. |
| Skin Protection: | Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove. |
| Ventilation: | Handle the material in an efficient fume hood. |
| Respirator: | If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134. |
| Additional Protection: | No additional protection required. |
| SECTION 9: Physical and Chemical Properties | |
|---|---|
| Color and Form: | pale yellow to colorless liquid |
| Molecular Weight: | 161.23 |
| Melting Point: | no data |
| Boiling Point: | 66°C (THF) |
| Vapor Pressure: | 0.173 Atm 20°C (THF) |
| Specific Gravity: | no data |
| Odor: | ethereal |
| Solubility in Water: | reacts with water |
| SECTION 10: Stability and Reactivity | |
|---|---|
| Stability: | air sensitive and moisture sensitive |
| Hazardous Polymerization: | no hazardous polymerization |
| Conditions to Avoid: | exposure to air and contact with an ignition source |
| Incompatibility: | water, oxidizing agents, halogens, air and mineral acids |
| Decomposition Products: | carbon monoxide, carbon dioxide, nitrogen oxides, phosphorous oxides and organic fumes |
| SECTION 11: Toxicological Information | |
|---|---|
| RTECS Data: | Title compound: No information available in the RTECS files. THF: Inhalation(human); TCLo: 25000ppm. Oral(rat); LD50: 1650mg/kg. Inhalation(rat); LC50: 21000ppm/3H. Intraperitoneal(rat); LD50: 2900mg/kg. Inhalation(mouse); LCLo: 24000mg/m3/2H. Inhalation(rabbit); LC: >1200ppm/4H. Oral(guinea pig); LDLo: 500mg/kg. Inhalation(rat); TCLo: 1800ppm/6H/2Y-I. |
| Carcinogenic Effects: | THF: Insufficient data |
| Mutagenic Effects: | THF: Possible mutagen |
| Tetratogenic Effects: | THF: Possible reproductive effector |
| SECTION 12: Ecological Information | |
|---|---|
| Ecological Information: | No information available |
| SECTION 13: Disposal Considerations | |
|---|---|
| Disposal: | Dispose of according to local, state and federal regulations. |
| SECTION 14: Transportation | |
|---|---|
| Shipping Name (CFR): | Flammable liquids, N.O.S. |
| Hazard Class (CFR): | 3 |
| Additional Hazard Class (CFR): | NA |
| Packaging Group (CFR): | I |
| UN ID Number (CFR): | UN# 1993 |
| Shipping Name (IATA): | Flammable liquid, N.O.S. |
| Hazard Class (IATA): | 3 |
| Additional Hazard Class (IATA): | NA |
| Packaging Group (IATA): | I |
| UN ID Number (IATA): | UN# 1993 |
| SECTION 15: Regulatory Information | |
|---|---|
| TSCA: | Title compound: Not listed in the TSCA inventory. |
| SARA (Title 313): | Title compound not listed |
| Second Ingredient: | THF: Listed in the TSCA inventory. Not regulated under SARA 313. |
| Third Ingredient: | none |
| SECTION 16: Other Information | |
|---|---|
| Disclaimer: | The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information. |
| Preparation Date: | 1/11/2012 |
| Revision Date: | 1/11/2012 |
