Product Catalog

15-0411

Phosphorus › (-)-1,2-Bis((2S,5S)-2,5-di-i-propylphospholano)benzene, 98+% (S,S)-i-Pr-DUPHOS

Stability: air sensitive

Physical Characteristics: melting point 40°C, spec. rotation -85° (c 1, hexane)

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SECTION 1: Product Identification
Chemical Name:	(-)-1,2-Bis((2S,5S)-2,5-di-i-propylphospholano)benzene, 98+% (S,S)-i-Pr-DUPHOS
Product Number:	15-0411
CAS Registry Number:	147253-69-8
Formula:	C26H44P2
EINECS Number:	none
Chemical Family:	organophosphine ligand
Synonym:	(S,S)-iPr DuPhos Ligand

SECTION 2: Composition and Information on Ingredients
Ingredient	CAS Number	Percent	ACGIH (TWA)	OSHA (PEL)
Title Compound	147253-69-8	100	no data	no data

SECTION 3: Hazards Identification
Emergency Overview:	Irritating to eyes and skin. May be harmful if swallowed or inhaled.
Primary Routes of Exposure:	Ingestion
Eye Contact:	Causes mild irritation of the eyes.
Skin Contact:	Causes slight irritation of the skin.
Inhalation:	Inhalation of dust may lead to irritation of the respiratory tract.
Ingestion:	No information is available on the physiological effects of ingestion. May be harmful if swallowed.
Acute Health Effects:	Irritating to eyes and skin. May be harmful if swallowed or inhaled.
Chronic Health Effects:	No information available on long-term chronic effects.
NTP:	No
IARC:	No
OSHA:	No

SECTION 4: First Aid Measures
Eye Exposure:	Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention.
Skin Exposure:	Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists.
Inhalation:	Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Ingestion:	Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:	no data
Autoignition Temperature:	no data
Explosion Limits:	no data
Extinguishing Medium:	carbon dioxide, dry powder or foam
Special Fire Fighting Procedures:	If this material is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus and full protective clothing.
Hazardous Combustion and Decomposion Products:	If involved in a fire this material may emit toxic organic fumes.
Unusual Fire or Explosion Hazards:	No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:	Small spills can be mixed with vermiculite or sodium carbonate and swept up.

SECTION 7: Handling and Storage
Handling and Storage:	Store in a tightly sealed container under an inert atmosphere of nitrogen. Keep away from heat and direct sunlight. Prolonged exposure to air may result in the degradation of the product.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:	Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:	Wear protective clothing and gloves.
Ventilation:	Material may form a fine dust. If possible, handle the material in an efficient fume hood.
Respirator:	If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Additional Protection:	No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:	white xtl.
Molecular Weight:	418.58
Melting Point:	40°C
Boiling Point:	no data
Vapor Pressure:	no data
Specific Gravity:	no data
Odor:	none
Solubility in Water:	insoluble

SECTION 10: Stability and Reactivity
Stability:	air sensitive solid
Hazardous Polymerization:	no hazardous polymerization
Conditions to Avoid:	prolonged contact with air
Incompatibility:	oxidizing agents and halogens
Decomposition Products:	carbon dioxide, carbon monoxide, phosphorus pentoxide, and organic fumes.

SECTION 11: Toxicological Information
RTECS Data:	No information available in the RTECS files.
Carcinogenic Effects:	No data available
Mutagenic Effects:	No data available
Tetratogenic Effects:	No data available

SECTION 12: Ecological Information
Ecological Information:	No information available

SECTION 13: Disposal Considerations
Disposal:	Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):	Non-hazardous
Hazard Class (CFR):	NA
Additional Hazard Class (CFR):	NA
Packaging Group (CFR):	NA
UN ID Number (CFR):	NA
Shipping Name (IATA):	Non-hazardous
Hazard Class (IATA):	NA
Additional Hazard Class (IATA):	NA
Packaging Group (IATA):	NA
UN ID Number (IATA):	NA

SECTION 15: Regulatory Information
TSCA:	Not listed in the TSCA inventory.
SARA (Title 313):	Title compound not listed.
Second Ingredient:	none
Third Ingredient:	none

SECTION 16: Other Information
Disclaimer:	The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information.
Preparation Date:	2/26/2001
Revision Date:	9/29/2004