CAS Number: 111-40-0
Product Catalog

07-0400

Nitrogen › Diethylenetriamine, min. 95% DIEN

Stability: air sensitive

Safety: Hazardous

Physical Characteristics: melting point -35°C, boiling point 199-209°C, flash point 202°F, density 0.955

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SECTION 1: Product Identification
Chemical Name:	Diethylenetriamine, min. 95% DIEN
Product Number:	07-0400
CAS Registry Number:	111-40-0
Formula:	NH2CH2CH2NHCH2CH2NH2
EINECS Number:	203-865-4
Chemical Family:	organic amine
Synonym:	Bis(2-aminoethyl)amine, Diethylenetriamine, 1,2-Ethanediamine

SECTION 2: Composition and Information on Ingredients
Ingredient	CAS Number	Percent	ACGIH (TWA)	OSHA (PEL)
Title Compound	111-40-0	100	1ppm	no data

SECTION 3: Hazards Identification
Emergency Overview:	Corrosive to skin, eyes and mucous membranes. May cause damage to the kidneys and liver. Harmful through skin absorption, inhalation, and if swallowed.
Primary Routes of Exposure:	Ingestion, inhalation, skin and eyes.
Eye Contact:	Corrosive to eyes. Contact may result in permanent damage or vision loss.
Skin Contact:	Corrosive to skin. Harmful through skin absorption. May cause sensitization by skin contact.
Inhalation:	Harmful by inhalation. Low vapor pressure makes extensive exposure unlikely.
Ingestion:	Ingestion of large amounts causes burns to the mouth, throat and esophagus.
Acute Health Effects:	Corrosive to skin, eyes and mucous membranes. Harmful through skin absorption, by inhalation, and if swallowed. May cause damage to kidneys and liver.
Chronic Health Effects:	Repeated exposure may cause liver and kidney effects. Risk of skin and airways sensitization.
NTP:	No
IARC:	No
OSHA:	No

SECTION 4: First Aid Measures
Eye Exposure:	Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention.
Skin Exposure:	Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists.
Inhalation:	Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Ingestion:	Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:	208°F
Autoignition Temperature:	358°C
Explosion Limits:	2.0-6.7%
Extinguishing Medium:	dry chemical, carbon dioxide, water fog, or foam.
Special Fire Fighting Procedures:	If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus and full protective clothing.
Hazardous Combustion and Decomposion Products:	If involved in a fire this material may emit toxic and corrosive organic fumes.
Unusual Fire or Explosion Hazards:	No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:	Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and swept up.

SECTION 7: Handling and Storage
Handling and Storage:	Store the material in a tightly sealed container in a cool, dry place.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:	Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:	Wear appropriate chemical resistant gloves and clothing.
Ventilation:	If possible, handle the material in an efficient fume hood.
Respirator:	If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Additional Protection:	No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:	colorless liq.
Molecular Weight:	103.17
Melting Point:	-35°C
Boiling Point:	199-209°C
Vapor Pressure:	<1mm (20°C)
Specific Gravity:	0.955
Odor:	fishy odor
Solubility in Water:	soluble

SECTION 10: Stability and Reactivity
Stability:	May discolor on long exposure to air
Hazardous Polymerization:	no hazardous polymerization
Conditions to Avoid:	contact with concentrated acids
Incompatibility:	oxidizing agents, nitric acid, perchloric acid, sulfuric acid and halogens.
Decomposition Products:	carbon monoxide, carbon dioxide, nitrogen oxides and organic fumes.

SECTION 11: Toxicological Information
RTECS Data:	Administration onto the skin (rabbit); Open irritation test: 500 mg. Administration onto the skin (rabbit); Standard Draize test: 500 mg. Oral (rat); LD50: 1080 mg/kg. Inhalation (rat); LCLo: 70mg/m3/4H. Intraperitoneal (rat); LD50: 74 mg/kg. Unreported (rat);LD50: 970 mg/kg. Intraperitoneal (mouse); LD50: 71 mg/kg. Unreported (mouse); LD50: 970 mg/kg. Administration onto the skin (rabbit); LD50: 1090 mg/kg. Unreported (rabbit); LD50: 970 mg/kg. Administration onto the skin (guinea pig); LD50: 170 uL/kg. Unreported (guinea pig); LD50: 600 mg/kg. Oral (rabbit); TDLo: 1820 mg/kg/26W-I.
Carcinogenic Effects:	no data
Mutagenic Effects:	no data
Tetratogenic Effects:	no data

SECTION 12: Ecological Information
Ecological Information:	No information available

SECTION 13: Disposal Considerations
Disposal:	Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):	Diethylenetriamine
Hazard Class (CFR):	8
Additional Hazard Class (CFR):	NA
Packaging Group (CFR):	II
UN ID Number (CFR):	UN# 2079
Shipping Name (IATA):	Diethylenetriamine
Hazard Class (IATA):	8
Additional Hazard Class (IATA):	NA
Packaging Group (IATA):	II
UN ID Number (IATA):	UN# 2079

SECTION 15: Regulatory Information
TSCA:	Listed in the TSCA inventory.
SARA (Title 313):	Title compound not listed.
Second Ingredient:	none
Third Ingredient:	none

SECTION 16: Other Information
Disclaimer:	The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information.
Preparation Date:	5/23/2004
Revision Date:	9/22/2011