SECTION 1: Product Identification
Chemical Name: n-Butyltin trichloride, min. 95%
Product Number: 93-5004
CAS Registry Number: 1118-46-3
Formula: C4H9SnCl3
EINECS Number: 214-263-6
Chemical Family: organotin compound
Synonym: Monobutyltin trichloride
SECTION 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title Compound 1118-46-3 100 0.1mg/m3 0.1mg/m3
SECTION 3: Hazards Identification
Emergency Overview: Organo tin compounds may act as delayed poisons, causing headache, dizziness; psycho-neurologic disturbances; sore throat, vomiting; urine retention; vision impairment; skin burns, liver and kidney damage.
Primary Routes of Exposure: Ingestion, inhalation, skin, eyes
Eye Contact: Causes severe burns to the eyes and blindness.
Skin Contact: Prolonged contact will cause redness and corrosive acid burns to the skin.
Inhalation: Corrosive to the nose, mucous membranes and respiratory tract. High doses may cause long term neurological damage.
Ingestion: Delayed and permanent psycho-neurologic disturbances; impairment of vision, unsteadiness, nausea and vomiting.
Acute Health Effects: Corrosive to skin, eyes and mucous membranes. Ingestion of certain organotin compounds may cause delayed poisoning (4 days) with cerebral edema causing damage to the central nervous system.
Chronic Health Effects: Repeated exposure to certain organic tin compounds may cause problems with vision, skin, respiratory system, central nervous system, liver, kidneys, urinary tract, and blood.
NTP: No
IARC: No
OSHA: No
SECTION 4: First Aid Measures
Eye Exposure: Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention.
Skin Exposure: Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists.
Inhalation: Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Ingestion: Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel.
SECTION 5: Fire Fighting Measures
Flash Point: 178°F
Autoignition Temperature: no data
Explosion Limits: no data
Extinguishing Medium: carbon dioxide, foam or dry powder
Special Fire Fighting Procedures: Fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus and full protective clothing.
Hazardous Combustion and Decomposion Products: carbon monoxide, carbon dioxide, soot, organic fumes and tin compounds.
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.
SECTION 6: Accidental Release Measures
Spill and Leak Procedures: Small spills can be neutralized with powdered sodium bicarbonate, lime, or calcium carbonate and swept up. Large spills in areas not adequately ventilated will require an evacuation of site. Emergency response teams will require self-contained breathing apparatus.
SECTION 7: Handling and Storage
Handling and Storage: Store in a cool, dry, well ventilated area away from heat and direct sunlight. Keep containers tightly sealed.
SECTION 8: Exposure Controls and Personal Protection
Eye Protection: Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection: Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.
Ventilation: Work with this product in a well-ventilated area, preferably a fume hood.
Respirator: If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Additional Protection: No additional protection required.
SECTION 9: Physical and Chemical Properties
Color and Form: colorless to yellow liq.
Molecular Weight: 282.17
Melting Point: -63°C
Boiling Point: 98°C /10 mm
Vapor Pressure: no data
Specific Gravity: 1.693
Odor: irritating odor
Solubility in Water: insoluble
SECTION 10: Stability and Reactivity
Stability: moisture sensitive
Hazardous Polymerization: no hazardous polymerization
Conditions to Avoid: none
Incompatibility: strong oxidizing agents and halogens
Decomposition Products: carbon dioxide, carbon monoxide, hydrogen chloride, tin oxide, and organic fumes.
SECTION 11: Toxicological Information
RTECS Data: Administration onto the skin (rabbit); Standard Draize test: 750 ug/24H. Administration into the eye (rabbit); 50 ug/24H. Oral (rat); LD50: 2140 mg/kg. Oral (rat); TDLo: 3 gm/kg.
Carcinogenic Effects: No data available
Mutagenic Effects: Mutagen
Tetratogenic Effects: Reproductive effector
SECTION 12: Ecological Information
Ecological Information: No information available
SECTION 13: Disposal Considerations
Disposal: Dispose of according to federal, state, and local regulations.
SECTION 14: Transportation
Shipping Name (CFR): Corrosive liquids, Acidic, Organic, N.O.S.
Hazard Class (CFR): 8
Additional Hazard Class (CFR): NA
Packaging Group (CFR): II
UN ID Number (CFR): UN# 3265
Shipping Name (IATA): Corrosive liquid, Acidic, Organic, N.O.S.
Hazard Class (IATA): 8
Additional Hazard Class (IATA): NA
Packaging Group (IATA): II
UN ID Number (IATA): UN# 3265
SECTION 15: Regulatory Information
TSCA: Listed in the TSCA inventory.
SARA (Title 313): Title compound not listed.
Second Ingredient: none
Third Ingredient: none
SECTION 16: Other Information
Disclaimer: The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information.
Preparation Date: 10/02/2002
Revision Date: 12/16/2011