SECTION 1: Product Identification
Chemical Name: Tetrakis(dimethylamino)titanium(IV), 99% TDMAT
Product Number: 93-2240
CAS Registry Number: 3275-24-9
Formula: Ti[N(CH3)2]4
EINECS Number: 221-904-3
Chemical Family: metal amide complex
Synonym: none
SECTION 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title Compound 3275-24-9 100 no data no data
SECTION 3: Hazards Identification
Emergency Overview: Flammable liquid and vapor. Inhalation may cause dizziness and headache. Corrosive to eyes, skin and mucous membranes. Harmful if swallowed, inhaled or absorbed through the skin.
Primary Routes of Exposure: Eye, skin and inhalation
Eye Contact: Causes burns to the eyes.
Skin Contact: Causes mild to severe irritation of the skin. Prolonged contact may dry the skin and lead to rashes or more severe irritation.
Inhalation: Corrosive to the nose, mucous membranes and respiratory tract.
Ingestion: Corrosive to mouth, throat and stomach. No information available on the physiological effects of ingestion.
Acute Health Effects: Corrosive to skin, eyes and mucous membranes.
Chronic Health Effects: No information available on long term chromic effects.
NTP: No
IARC: No
OSHA: No
SECTION 4: First Aid Measures
Eye Exposure: Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim will need assistance in keeping their eye lids open. Get immediate medical attention.
Skin Exposure: Wash the affected area immediately with water. Remove contaminated clothing if necessary. Seek medical assistance if irritation persists.
Inhalation: Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Ingestion: Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting if directed by medical personnel.
SECTION 5: Fire Fighting Measures
Flash Point: -22°F
Autoignition Temperature: no data
Explosion Limits: no data
Extinguishing Medium: dry chemical, carbon dioxide, or foam.
Special Fire Fighting Procedures: If this material is involved in a fire, fire fighters should be equipped with a NIOSH-approved positive pressure self-contained breathing and full protective clothing.
Hazardous Combustion and Decomposion Products: If involved in a fire, this material may release toxic and irritating fumes.
Unusual Fire or Explosion Hazards: Flammable liquid. No unusual fire or explosion hazards.
SECTION 6: Accidental Release Measures
Spill and Leak Procedures: Small spills can be absorbed into vermiculite or other suitable adsorbent. Larger spills, eliminate all potential ignition sources. Material may begin to hydrolyze forming irritating and noxious fumes. Absorb the material into sawdust or clay. Emergency team must wear a self-contained breathing apparatus.
SECTION 7: Handling and Storage
Handling and Storage: Store in a cool, dry, well-ventilated area away from heat and direct sunlight. Keep containers tightly sealed. This product will react with atmospheric moisture and chemically degrade. Transfer material under an inert atmosphere of nitrogen or argon.
SECTION 8: Exposure Controls and Personal Protection
Eye Protection: Always wear safety glasses. If pouring or transferring this substance wear a face shield for additional protection.
Skin Protection: Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.
Ventilation: Work with this product in a well-ventilated area, preferably a fume hood.
Respirator: If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134
Additional Protection: No additional protection required.
SECTION 9: Physical and Chemical Properties
Color and Form: yellow to orange liq.
Molecular Weight: 224.20
Melting Point: no data
Boiling Point: 50°C /0.5 mm
Vapor Pressure: no data
Specific Gravity: 0.96
Odor: amine odor
Solubility in Water: reacts violently with water
SECTION 10: Stability and Reactivity
Stability: moisture-sensitive liquid
Hazardous Polymerization: no hazardous polymerization
Conditions to Avoid: contact with moisture
Incompatibility: water, mineral acids, halogens and oxidizing agents
Decomposition Products: carbon dioxide, carbon monoxide, nitrogen oxides, organic fumes, and titanium oxide.
SECTION 11: Toxicological Information
RTECS Data: No information available in the RTECS files.
Carcinogenic Effects: No reported carcinogenic effects
Mutagenic Effects: No reported mutagenic effects
Tetratogenic Effects: No reported tetratogenic effects
SECTION 12: Ecological Information
Ecological Information: No information available
SECTION 13: Disposal Considerations
Disposal: Dispose of according to local, state and federal regulations. For purposes of shipping waste material see the section 14 in this document on transportation.
SECTION 14: Transportation
Shipping Name (CFR): Organometallic Substance, Liquid,Water-reactive,Flammable
Hazard Class (CFR): 4.3
Additional Hazard Class (CFR): 3
Packaging Group (CFR): II
UN ID Number (CFR): UN# 3399
Shipping Name (IATA): Organometallic substance, Liquid,Water-reactive,Flammable
Hazard Class (IATA): 4.3
Additional Hazard Class (IATA): 3
Packaging Group (IATA): II
UN ID Number (IATA): UN# 3399
SECTION 15: Regulatory Information
TSCA: Listed in the TSCA inventory.
SARA (Title 313): Not reportable under SARA Title 313.
Second Ingredient: none
Third Ingredient: none
SECTION 16: Other Information
Disclaimer: The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information.
Preparation Date: 8/21/2000
Revision Date: 10/13/2014